Name | Popov, Dr. Alexey |
---|---|
Department | Nanoscale Chemistry |
Position | Group leader (Fullerenes) |
Phone Number | +49-351-4659-871 |
A.Popov(at)ifw-dresden.de |
2010-present: group-leader, IFW Dresden, Dept. Nanoscale Chemistry
2008-2010: Humboldt Fellow, IFW Dresden
2006-2008: senior researcher, Chemistry Department, Moscow State University
2003-2005: junior researcher, Chemistry Department, Moscow State University
1999-2003: Ph. D. in Physical Chemistry at Chemistry Department, Moscow State University
1994-1999: student, Chemistry Department, Moscow State University
F. Paschke, T. Birk, S. M. Avdoshenko, F. Liu, A. A. Popov, M. Fonin. Imaging the Single-Electron Ln–Ln Bonding Orbital in a Dimetallofullerene Molecular Magnet. Small 2021, in press, 2105667. DOI: 10.1002/smll.202105667
Y. Wang, G. Velkos, N. J. Israel, M. Rosenkranz, B. Büchner, F. Liu, A. A. Popov. Electrophilic Trifluoromethylation of Dimetallofullerene Anions en Route to Air-Stable Single-Molecule Magnets with High Blocking Temperature of Magnetization. J. Am. Chem. Soc. 2021, 143, 18139. DOI: 10.1021/jacs.1c07021
L. Spree, F. Liu, V. Neu, M. Rosenkranz, G. Velkos, Y. Wang, S. Schiemenz, J. Dreiser, P. Gargiani, M. Valvidares, C.-H. Chen, B. Büchner, S. M. Avdoshenko, A. A. Popov. Robust Single-Molecule Magnet Monolayers on Graphene and Graphite with Magnetic Hysteresis up to 28 K. Adv. Funct. Mater. 2021, 31, 2105516. DOI: 10. 1002/adfm.202105516
F. Paschke, T. Birk, V. Enenkel, F. Liu, V. Romankov, J. Dreiser, A. A. Popov, M. Fonin. Exceptionally High Blocking Temperature of 17 K in a Surface-Supported Molecular Magnet. Adv. Mater. 2021, 33, 2102844. DOI: 10.1002/adma.202102844
M. Zalibera, F. Ziegs, S. Schiemenz, V. Dubrovin, W. Lubitz, A. Savitsky, S. Deng, X.-B. Wang, S. Avdoshenko, A. A. Popov. Metallofullerene photoswitches driven by photoinduced fullerene-to-metal electron transfer. Chem. Sci. 2021, 12, 7818-7838. DOI: 10.1039/D0SC07045A
C.-H. Chen, L. Spree, E. Koutsouflakis, D. S. Krylov, F. Liu, A. Brandenburg, G. Velkos, S. Schimmel, S. M. Avdoshenko, A. Fedorov, E. Weschke, F. Choueikani, P. Ohresser, J. Dreiser, B. Büchner, A. A. Popov. Magnetic hysteresis at 10 K in single molecule magnet self-assembled on gold. Adv. Sci. 2021, 8 (5), 2000777. DOI: 10.1002/advs.202000777
Y. Hao, Y. Wang, V. Dubrovin, S. M. Avdoshenko, A. A. Popov, F. Liu. Caught in Phase Transition: Snapshot of the Metallofullerene Sc3N@C70 Rotation in the Crystal. J. Am. Chem. Soc. 2021, 143 (2), 612–616.DOI: 10.1021/jacs.0c10758
V. Martinez, B. Karadeniz, N. Biliškov, I. Lončarić, S. Muratović, D. Žilić, S. M. Avdoshenko, M. Roslova, A. A. Popov, K. Užarević. Tunable fulleretic sodalite MOFs: highly efficient and controllable entrapment of C60 fullerene via mechanochemistry. Chem. Mater. 2020, 32 (24), 10628–10640. DOI: 10.1021/acs.chemmater.0c03796
R. B. Zaripov, Y. E. Kandrashkin, K. M. Salikhov, B. Büchner, F. Liu, M. Rosenkranz, A. A. Popov, V. Kataev. Unusually large hyperfine structure of the electron spin levels in an endohedral dimetallofullerene and its spin coherent properties. Nanoscale 2020, 12, 20513-20521. DOI: 10.1039/D0NR06114J
D. Krylov, G. Velkos, C.-H. Chen, B. Büchner, A. Kostanyan, T. Greber, S. M. Avdoshenko, A. A. Popov. Magnetic hysteresis and strong ferromagnetic coupling of sulfur-bridged Dy ions in clusterfullerene Dy2S@C82. Inorg. Chem. Front. 2020, 7, 3521-3532. DOI: 10.1039/D0QI00771D
G. Velkos, W. Yang, Y.-R. Yao, S. M. Sudarkova, X.Y. Liu, B. Büchner, S. M. Avdoshenko, N. Chen, A. A. Popov. Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy2O@C72 and Dy2O@C74 with fused pentagon pairs and flexible Dy–(μ2-O)–Dy angle. Chem. Sci. 2020, 11, 4766-4774.DOI: 10.1039/D0SC00624F
D. S. Krylov, S. Schimmel, V. Dubrovin, F. Liu, T. T. N. Nguyen, L. Spree, C.-H. Chen, G. Velkos, C. Bulbucan, R. Westerström, M. Studniarek, J. Dreiser, C. Hess, B. Büchner, S. M. Avdoshenko, A. A. Popov. Substrate‐independent magnetic bistability in monolayers of single molecule magnet Dy2ScN@C80 on metals and insulator. Angew. Chem. Int. Ed. 2020, 59 (14), 5756-5764 DOI: 10.1002/anie.201913955
L. Spree, C. Schlesier, A. Kostanyan, R. Westerström, T. Greber, B. Büchner, S. Avdoshenko, A. A. Popov. Single molecule magnets DyM2N@C80 and Dy2MN@C80 (M = Sc, Lu): The impact of diamagnetic metals on the Dy3+ magnetic anisotropy, Dy∙∙∙Dy coupling, and mixing of molecular and lattice vibrations. Chem. Eur. J. 2020, 26, 2436-2449 .DOI: 10.1002/chem.201904879
F. Liu, L. Spree, D. S. Krylov, G. Velkos, S. M. Avdoshenko, A. A. Popov. Single-electron lanthanide-lanthanide bonds inside fullerenes toward robust redox-active molecular magnets. Acc. Chem. Res. 2019, 52 (10), 2981-2993. DOI: 10.1021/acs.accounts.9b00373
V. Dubrovin, A. A. Popov, S. Avdoshenko. Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism). Chem. Commun. 2019, 55, 13963-13966. DOI: 10.1039/C9CC06913E
W. Yang, G. Velkos, F. Liu, S. M. Sudarkova, Y. Wang, J. Zhuang, H. Zhang, X. Li, X. Zhang, B. Büchner, S. M. Avdoshenko, A. A. Popov, N. Chen. Single molecule magnetism with strong magnetic anisotropy and enhanced Dy∙∙∙Dy coupling in three isomers of Dy-oxide clusterfullerene Dy2O@C82. Adv. Sci. 2019, 1901352. DOI: 10.1002/advs.201901352
F. Liu, G. Velkos, D. S. Krylov, L. Spree, M. Zalibera, R. Ray, N. A. Samoylova, C.-H. Chen, M. Rosenkranz, S. Schiemenz, F. Ziegs, K. Nenkov, A. Kostanyan, T. Greber, A. U. B. Wolter, M. Richter, B. Büchner, S. M. Avdoshenko, A. A. Popov. Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal-metal bond. Nat. Commun. 2019, 10, 571. DOI: 10.1038/s41467-019-08513-6
G. Velkos, D. S. Krylov, K. Kirkpatrick, L. Spree, V. Dubrovin, B. Büchner, S. M. Avdoshenko, V. Bezmelnitsyn, S. Davis, P. Faust, J. Duchamp, H. C. Dorn, A. A. Popov. High blocking temperature of magnetization and giant coercivity in the azafullerene Tb2@C79N with a single-electron Tb–Tb bond. Angew. Chem. Int. Ed. 2019, 58, 5891. DOI: 10.1002/anie.201900943
F. Paschke, T. Birk, S. M. Avdoshenko, F. Liu, A. A. Popov, M. Fonin. Imaging the Single-Electron Ln–Ln Bonding Orbital in a Dimetallofullerene Molecular Magnet. Small 2021, in press, 2105667.DOI: 10.1002/smll.202105667
Y. Wang, G. Velkos, N. J. Israel, M. Rosenkranz, B. Büchner, F. Liu, A. A. Popov. Electrophilic Trifluoromethylation of Dimetallofullerene Anions en Route to Air-Stable Single-Molecule Magnets with High Blocking Temperature of Magnetization. J. Am. Chem. Soc. 2021, 143, 18139. DOI: 10.1021/jacs.1c07021
L. Spree, F. Liu, V. Neu, M. Rosenkranz, G. Velkos, Y. Wang, S. Schiemenz, J. Dreiser, P. Gargiani, M. Valvidares, C.-H. Chen, B. Büchner, S. M. Avdoshenko, A. A. Popov. Robust Single-Molecule Magnet Monolayers on Graphene and Graphite with Magnetic Hysteresis up to 28 K. Adv. Funct. Mater. 2021, 31, 2105516. DOI: 10. 1002/adfm.202105516
F. Paschke, T. Birk, V. Enenkel, F. Liu, V. Romankov, J. Dreiser, A. A. Popov, M. Fonin. Exceptionally High Blocking Temperature of 17 K in a Surface-Supported Molecular Magnet. Adv. Mater. 2021, 33, 2102844. DOI: 10.1002/adma.202102844
R. Westerström, V. Dubrovin, K. Junghans, C. Schlesier, B. Büchner, S. M. Avdoshenko, A. Popov, A. Kostanyan, J. Dreiser, T. Greber. Precise measurement of angles between two magnetic moments and their configurational stability in single-molecule magnets. Phys. Rev. B.2021, 104 (22), 224401. DOI: 10.1103/PhysRevB.104.224401
Y. E. Kandrashkin, R. Zaripov, F. Liu, B. Büchner, V. Kataev, A. A Popov. Temperature-Dependent Dynamics of Endohedral Fullerene Sc2@C80(CH2Ph) Studied by EPR Spectroscopy. Phys. Chem. Chem. Phys. 2021, 23, 18206-18220. DOI: 10.1039/D1CP02237G
C.-H. Chen, L. Spree, E. Koutsouflakis, D. S. Krylov, F. Liu, A. Brandenburg, G. Velkos, S. Schimmel, S. M. Avdoshenko, A. Fedorov, E. Weschke, F. Choueikani, P. Ohresser, J. Dreiser, B. Büchner, A. A. Popov. Magnetic hysteresis at 10 K in single molecule magnet self-assembled on gold. Adv. Sci. 2021, 202000777. DOI: 10.1002/advs.202000777
Y. Hao, Y. Wang, V. Dubrovin, S. M. Avdoshenko, A. A. Popov, F. Liu. Caught in Phase Transition: Snapshot of the Metallofullerene Sc3N@C70 Rotation in the Crystal. J. Am. Chem. Soc. 2021, 143 (2), 612–616. DOI: 10.1021/jacs.0c10758
V. Dubrovin, A. A. Popov, S. M. Avdoshenko. Valence electrons in lanthanide-based single-atom magnets: a paradigm shift in 4f-magnetism modeling and design. Inorg. Chem. Front. 2021, 8, 2373-2384. DOI: 10.1039/D0QI01148G
M. Zalibera, F. Ziegs, S. Schiemenz, V. Dubrovin, W. Lubitz, A. Savitsky, S. Deng, X.-B. Wang, S. Avdoshenko, A. A. Popov. Metallofullerene photoswitches driven by photoinduced fullerene-to-metal electron transfer. Chem. Sci. 2021, 12, 7818-7838. DOI: 10.1039/D0SC07045A
A. Kostanyan, C. Schlesier, R. Westerström, J. Dreiser, F. Fritz, B. Büchner, A. A. Popov, C. Piamonteze, T. Greber. Gadolinium as an accelerator for reaching thermal equilibrium and its influence on the ground state of Dy2GdN@C80 single-molecule magnets. Phys. Rev. B. 2021, 103, 014404. DOI: 10.1103/PhysRevB.103.014404
F. Jin, J. Xin, R. Guan, X.-M. Xie, M. Chen, Q. Zhang, A. A. Popov, S.-Y. Xie, S. Yang. Stabilizing Three-Center Single-Electron Metal-Metal Bond in a Fullerene Cage. Chem. Sci. 2021, 12, 6890-6895. DOI: 10.1039/D1SC00965F
J.-J. Zhang, L. Yang, F. Liu, Y. Fu, J. Liu, A. A. Popov, J. Ma, X. Feng. A Modular Cascade Synthetic Strategy Toward Structurally Constrained Boron‐doped Polycyclic Aromatic Hydrocarbons. Angew. Chem. Int. Ed. 2021, 60, 25695. DOI: 10.1002/anie.202109840
B. J. Eleazer, H. D. A. C. Jayaweera, G. B. Gange, M. D. Smith, C. R. Martin, K. C. Park, A. A. Popov, D. V. Peryshkov. Bimetallic Ru-Pd and Trimetallic Ru-Pd-Cu Assemblies on the Carborane Cluster Surface. Inorg. Chem. 2021, 60 , 16911. DOI: 10.1021/acs.inorgchem.1c02799
L. P. Doctor, M. Naumann, F. Ziegs, B. Büchner, A. A. Popov, M. Knupfer. Strong photophysical diversity and the role of charge transfer excitons in transition metal phthalocyanine β-phases. J. Phys. Chem. C 2021, 125 (22), 12398-12404. DOI: 10.1021/acs.jpcc.1c02654
M. Gerwig, A. S. Ali, D. Neubert, S. Polster, U. Böhme, G. Franze, M. Rosenkranz, A. Popov, I. Ponomarev, M. P. M. Jank, C. Viehweger, E. Brendler, L. Frey, P. Kroll, E. Kroke. From cyclopentasilane to thin film transistors. Adv. Electron. Mater. 2021, 7 (2), 2000422. DOI: 10.1002/aelm.202000422
M. Richter, M. Borkowski, Y. Fu, E. Dmitrieva, A. A. Popov, J. Ma, T. Marszalek, W. Pisula, X. Feng. Synthesis and Self-Assembly Behavior of Double Ullazine-Based Polycyclic Aromatic Hydrocarbons. Organic Materials 2021, 3 (02), 198-203. DOI: 10.1055/a-1472-6852
M. Korb, X. Liu, S. Walz, J. Mahrholdt, A. A. Popov, H. Lang. Structural Variety of Iron Carbonyl Clusters Featuring Ferrocenylphosphines. Eur J. Inorg. Chem. 2021, 2017-2033. DOI: 10.1002/ejic.202100097
V. Martinez, B. Karadeniz, N. Biliškov, I. Lončarić, S. Muratović, D. Žilić, S. M. Avdoshenko, M. Roslova, A. A. Popov, K. Užarević. Tunable fulleretic sodalite MOFs: highly efficient and controllable entrapment of C60 fullerene via mechanochemistry. Chem. Mater. 2020, 32 (24), 10628–10640. DOI: 10.1021/acs.chemmater.0c03796
R. B. Zaripov, Y. E. Kandrashkin, K. M. Salikhov, B. Büchner, F. Liu, M. Rosenkranz, A. A. Popov, V. Kataev. Unusually large hyperfine structure of the electron spin levels in an endohedral dimetallofullerene and its spin coherent properties. Nanoscale 2020, 12, 20513-20521. DOI: 10.1039/D0NR06114J
W. Niu, J. Ma, P. Soltani, W. Zheng, F. Liu, A. A. Popov, J. J. Weigand, H. Komber, E. Poliani, C. Casiraghi, J. Droste, M. R. Hansen, S. Osella, D. Beljonne, M. Bonn, H. I. Wang, X. Feng, J. Liu, Y. Mai. A Curved Graphene Nanoribbon with Multi-Edge Structure and High Intrinsic Charge Carrier Mobility. J. Am. Chem. Soc. 2020, 142 (43), 18293–18298. DOI: 10.1021/jacs.0c07013
H. Chang, H. Liu, E. Dmitrieva, Q. Chen, J. Ma, P. He, P. Liu, A. A Popov, X. Cao, X.-Y. Wang, Y. Zou, A. Narita, K. Muellen, H. Peng, Y. Hu. Furan-Containing Double Tetraoxa[7]helicene and its Radical Cation. Chem. Commun.2020, 56, 15181–15194. DOI: 10.1039/D0CC06970A
P. Rietsch, S. Sobottka, K. Hoffmann, A. Popov, P. Hildebrandt, B. Sarkar, U. Resch-Genger, S. Eigler. Between Aromatic and Quinoid Structure: A symmetric UV to Vis/NIR Benzothiadiazole Redox‐Switch. Chem. Eur. J. 2020, 26 (72), 17361–17365. DOI: 10.1002/chem.202004009
F. Hansen, M. Wels, S. Froeschke, A. A. Popov, D. Wolf, B. Büchner, P. Schmidt, S. Hampel. Thermodynamic evaluation and chemical vapor transport of few-layer WTe2. Cryst. Growth Des. 2020, 20 (11), 7341–7349. DOI: 10.1021/acs.cgd.0c01004
V. Dubrovin, A. A. Popov, S. M. Avdoshenko. Valence Electrons in Lanthanide-Based Single-Atom Magnets: A Paradigm Shift in 4f-Magnetism Modeling and Design. ChemRxiv. Preprint 2020. DOI: 10.26434/chemrxiv.12800096.v1
M. Schulz, N. Hagmeyer, F. Wehmeyer, G. Lowe, M. Rosenkranz, B. Seidler, A. Popov, C. Streb, J. G. Vos, B. Dietzek. Photoinduced charge accumulation and prolonged multielectron storage for the separation of light and dark reaction. J. Am. Chem. Soc. 2020, 142 (37), 15722-15728. DOI: 10.1021/jacs.0c03779
D. Krylov, G. Velkos, C.-H. Chen, B. Büchner, A. Kostanyan, T. Greber, S. M. Avdoshenko, A. A. Popov. Magnetic hysteresis and strong ferromagnetic coupling of sulfur-bridged Dy ions in clusterfullerene Dy2S@C82. Inorg. Chem. Front. 2020, 7, 3521-3532. DOI: 10.1039/D0QI00771D
A. D. Pykhova, O. O. Semivrazhskaya, N. A. Samoylova, A. V. Rybalchenko, M. Rosenkranz, I. N. Ioffe, A. A Popov, A. A. Goryunkov. Addition of CF2 group to endohedral fullerene Sc3N@Ih-C80. Dalton Trans. 2020, 49, 9137-9147. DOI: 10.1039/D0DT01513J
G. Velkos, W. Yang, Y.-R. Yao, S. M. Sudarkova, X.Y. Liu, B. Büchner, S. M. Avdoshenko, N. Chen, A. A. Popov. Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy2O@C72 and Dy2O@C74 with fused pentagon pairs and flexible Dy–(μ2-O)–Dy angle. Chem. Sci. 2020, 11, 4766-4772. DOI: 10.1039/D0SC00624F
A. Kostanyan, R. Westerström, D. Kunhardt, B. Büchner, A. A. Popov, T. Greber. Sub-Kelvin hysteresis of the dilanthanide single-molecule magnet Tb2ScN@C80. Phys. Rev. B 2020, 101, 134429. DOI: 10.1103/PhysRevB.101.134429
D. S. Krylov, S. Schimmel, V. Dubrovin, F. Liu, T. T. N. Nguyen, L. Spree, C.-H. Chen, G. Velkos, C. Bulbucan, R. Westerström, M. Studniarek, J. Dreiser, C. Hess, B. Büchner, S. M. Avdoshenko, A. A. Popov. Substrate‐independent magnetic bistability in monolayers of single molecule magnet Dy2ScN@C80 on metals and insulator. Angew. Chem. Int. Ed. 2020, 59, 5756-5764. DOI: 10.1002/anie.201913955
J. Ma, Y. Fu, E. Dmitrieva, F. Liu, H. Komber, F. Hennersdorf, A. A. Popov, J. J. Weigand, J. Liu, X. Feng. Helical Nanographenes Containing an Azulene Unit: Synthesis, Crystal Structures, and Properties. Angew. Chem. Int. Ed. 2020, 59, 5637-5642. DOI: 10.1002/anie.201914716
L. Spree, C. Schlesier, A. Kostanyan, R. Westerström, T. Greber, B. Büchner, S. Avdoshenko, A. A. Popov. Single molecule magnets DyM2N@C80 and Dy2MN@C80 (M = Sc, Lu): The impact of diamagnetic metals on the Dy3+ magnetic anisotropy, Dy∙∙∙Dy coupling, and mixing of molecular and lattice vibrations. Chem. Eur. J. 2020, 26, 2436-2449. DOI: 10.1002/chem.201904879
E. Dmitrieva, X. Yu, A. Popov, H. Hartmann. On the electrochemical reduction of 4‐(thiazol‐2‐ylazo)‐substituted 1‐chloronaphthalenes: formation and characterization of stable radical anions. ChemElectroChem 2020, 7 (7), 1666-1671. DOI: 10.1002/celc.202000121
S. N. Intorp, M. Hodecker, M. Müller, O. Tverskoy, M. Rosenkranz, E. Dmitrieva, A. A. Popov, F. Rominger, J. Freudenberg, A. Dreuw, U. H. Bunz. Quinoidal Azaacenes: 99% Diradical Character. Angew. Chem. Int. Ed. 2020, 59 (30), 12396-12401. DOI: 10.1002/anie.201915977
Ajayakumar M R, Y. Fu, F. Liu, H. Komber, V. Tkachova, C. Xu, S. Zhou, A. A. Popov, J. Liu, X. Feng. Tailoring Magnetic Feature in Zigzag‐Edged Nanographenes via Controlled Diels‐Alder Reactions. Chem. Eur. J. 2020, 26, 7497-7503. DOI: 10.1002/chem.202001130
M. Korb, X. Liu, S. Walz, M. Rosenkranz, E. Dmitrieva, A. A. Popov, H. Lang. (Electrochemical) Properties and Computational Investigations of Ferrocenyl-Substituted Fe3(µ3-PFc)2(CO)9 and Co4(µ4-PFc)2(CO)9 Clusters and their Reduced Species. Inorg. Chem. 2020, 59, 6147-6169. DOI: 10.1021/acs.inorgchem.0c00276
J. Melidonie, E. Dmitrieva, K. Zhang, Y. Fu, A. A. Popov, W. Pisula, R. Berger, J. Liu, X. Feng. Dipyrene-Fused Dicyclopenta[a,f]naphthalenes. J. Org. Chem. 2020, 85, 215-223. DOI: 10.1021/acs.joc.9b02626
F. Liu, L. Spree, D. S. Krylov, G. Velkos, S. M. Avdoshenko, A. A. Popov. Single-electron lanthanide-lanthanide bonds inside fullerenes toward robust redox-active molecular magnets. Acc. Chem. Res. 2019, 52 (10), 2981-2993. DOI: 10.1021/acs.accounts.9b00373
V. Dubrovin, A. A. Popov, S. Avdoshenko. Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism). Chem. Commun. 2019, 55, 13963-13966. DOI: 10.1039/C9CC06913E
R. B. Zaripov, S. M. Avdoshenko, I. Khairuzhdinov, K. M Salikhov, V. K. Voronkova, S. Weheabby, T. Rüffer, A. A. Popov, B. Büchner, V. Kataev. Effect of the Diamagnetic Single Crystalline Host on the Angular-Resolved Electron Nuclear Double Resonance Experiments: Case of Paramagnetic [nBu4N]2[Cu(opba)] Embedded in Diamagnetic [nBu4N]2[Ni(opba)]. J. Phys. Chem. Lett. 2019, 10, 6565-6571. DOI: 10.1021/acs.jpclett.9b02523
C. Schlesier, F. Liu, V. Dubrovin, L. Spree, B. Büchner, S. M. Avdoshenko, A. A Popov. Mixed dysprosium-lanthanide nitride clusterfullerenes DyM2N@C80-Ih and Dy2MN@C80-Ih (M = Gd, Er, Tm, and Lu): synthesis, molecular structure, and quantum motion of the endohedral nitrogen atom. Nanoscale 2019, 11, 13139. DOI: 10.1039/C9NR03593A
W. Yang, G. Velkos, F. Liu, S. M. Sudarkova, Y. Wang, J. Zhuang, H. Zhang, X. Li, X. Zhang, B. Büchner, S. M. Avdoshenko, A. A. Popov, N. Chen. Single molecule magnetism with strong magnetic anisotropy and enhanced Dy∙∙∙Dy coupling in three isomers of Dy-oxide clusterfullerene Dy2O@C82. Adv. Sci. 2019, 1901352. DOI: 10.1002/advs.201901352
D. Konarev, A. A. Popov, L. V. Zorina, S. S. Khasanov, R. N. Lyubovskaya. Molecular structure, magnetic and optical properties of endometallonitridofullerene Sc3N@Ih‐C80 in neutral, radical anion and dimeric anionic forms. Chem. Eur. J. 2019, 25 (65), 14858-14869. DOI: 10.1002/chem.201902782
F. Liu, G. Velkos, D. S. Krylov, L. Spree, M. Zalibera, R. Ray, N. A. Samoylova, C.-H. Chen, M. Rosenkranz, S. Schiemenz, F. Ziegs, K. Nenkov, A. Kostanyan, T. Greber, A. U. B. Wolter, M. Richter, B. Büchner, S. M. Avdoshenko, A. A. Popov. Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal-metal bond. Nat. Commun. 2019, 10, 571. DOI: 10.1038/s41467-019-08513-6
G. Velkos, D. S. Krylov, K. Kirkpatrick, L. Spree, V. Dubrovin, B. Büchner, S. M. Avdoshenko, V. Bezmelnitsyn, S. Davis, P. Faust, J. Duchamp, H. C. Dorn, A. A. Popov. High blocking temperature of magnetization and giant coercivity in the azafullerene Tb2@C79N with a single-electron Tb–Tb bond. Angew. Chem. Int. Ed. 2019, 58, 5891. DOI: 10.1002/anie.201900943
L. Spree, A. A. Popov. Recent advances in single molecule magnetism of dysprosium-metallofullerenes. Dalton Trans. 2019, 48, 2861. DOI: 10.1039/c8dt05153d
V. Dubrovin, L.-H. Gan, B. Büchner, A. A. Popov, S. M. Avdoshenko. Endohedral metal-nitride cluster ordering in metallofullerene-NiII(OEP) complexes and crystals: a theoretical study. Phys. Chem. Chem. Phys. 2019, 21, 8197. DOI: 10.1039/C9CP00634F
T. Greber, A. P. Seitsonen, A. Hemmi, J. Dreiser, R. Stania, F. Matsui, M. Muntwiler, A. A. Popov, R. Westerström. Circular dichroism and angular deviation in x-ray absorption spectra of Dy2ScN@C80 single molecule magnets on h-BN/Rh(111). Phys. Rev. Materials 2019, 3, 014409. DOI: 10.1103/PhysRevMaterials.3.014409
N. J. DeWeerd, E. V. Bukovsky, K. P. Castro, I. V. Kuvychko, A. A. Popov, S. H. Strauss, O. V. Boltalina. Steric and electronic effects of CF3 conformations in acene(CF3)n derivatives. J. Fluor. Chem. 2019, 221, 1-7. DOI: 10.1016/j.jfluchem.2019.02.010
K. P. Castro, E. V. Bukovsky, I. V. Kuvychko, N. J. DeWeerd, Y.-S. Chen, S. H. M. Deng, X.-B. Wang, A. A. Popov, S. H. Strauss, O. V. Boltalina. PAH/PAH(CF3)n Donor/Acceptor Charge-Transfer Complexes in Solution and in Solid-State Co-Crystals. Chem. Eur. J. 2019, 25 (59), 13547-13565. DOI: 10.1002/chem.201902712
J. Ma, K. Zhang, K. S. Schellhammer, Y. Fu, H. Komber, C. Xu, A. A. Popov, F. Hennersdorf, J. J. Weigand, S. Zhou, W. Pisula, F. Ortmann, R. F. J. Berger, J. Liu, X. Feng. Wavy-shaped Polycyclic Hydrocarbons with Controlled Aromaticity. Chem. Sci. 2019, 10, 4025. DOI: 10.1039/C8SC05416A
Y. Fu, K. Zhang, E. Dmitrieva, F. Liu, J. Ma, J. J. Weigand, A. A. Popov, R. Berger, W. Pisula, J. Liu, X. Feng. NBN-embedded polycyclic aromatic hydrocarbons containing pentagonal and heptagonal rings. Org. Lett. 2019, 21, 1354. DOI: 10.1021/acs.orglett.9b00057
M. Richter, Y. Fu, E. Dmitrieva, J. J. Weigand, A. A. Popov, R. Berger, J. Liu, X. Feng. A Polycyclic Aromatic Hydrocarbon Containing A Pyrrolopyridazine Core. ChemPlusChem 2019, 84, 613. DOI: 10.1002/cplu.201900031
S. N. Intorp, S. Kushida, E. Dmitrieva, A. A Popov, F. Rominger, J. Freudenberg, F. Hinkel, U. H. F. Bunz. True Blue Through Oxidation – A Thiaazulenic Heterophenoquinone as Electrochrome. Chem. Eur. J. 2019, 25, 5412. DOI: 10.1002/chem.201900535
M. Richter, S. Hahn, E. Dmitrieva, F. Rominger, A. Popov, U. H. F. Bunz, X. Feng, R. Berger. Helical Ullazine-Quinoxaline-Based Polycyclic Aromatic Hydrocarbons. Chem. Eur. J. 2019, 25 (5), 1345-1352. DOI: 10.1002/chem.201804751
S. M. Avdoshenko, F. Fritz, C. Schlesier, A. Kostanyan, J. Dreiser, M. Luysberg, A. A. Popov, C. Meyer, R. Westerström. Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods. Nanoscale 2018, 10, 18153-18160. DOI: 10.1039/C8NR05386C
A. Brandenburg, D. S. Krylov, A. Beger, A. U. B. Wolter, B. Büchner, A. A. Popov. Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism. Chem. Commun. 2018, 54, 10683-10686. DOI: 10.1039/C8CC04736G
C. Schlesier, L. Spree, A. Kostanyan, R. Westerström, A. Brandenburg, A. U. B. Wolter, S. Yang, T. Greber, A. A Popov. Strong carbon cage influence on the single molecule magnetism in Dy-Sc nitride clusterfullerenes. Chem. Commun. 2018, 54, 9730-9733. DOI: 10.1039/C8CC05029E
X. Zhang, W.-L. Li, L. Feng, X. Chen, A. Hansen, S. Grimme, S. Fortier, D.-C. Sergentu, T. Duignan, J. Autschbach, S. Wang, Y. Wang, G. Velkos, A. Popov, N. Aghdassi, S. Duhm, X. Li, J. Li, L. Echegoyen, W. H. E. Schwarz, N. Chen. A Diuranium Carbide Cluster Stabilized Inside a C80 Fullerene Cage. Nat. Commun. 2018, 9, 2753. DOI: 10.1038/s41467-018-05210-8
R. Stania, A. P. Seitsonen, D. Kunhardt, B. Büchner, A. A. Popov, M. Muntwiler, T. Greber. Electrostatic Interaction Across a Single Layer Carbon Shell. J. Phys. Chem. Lett. 2018, 9, 3586-3590. DOI: 10.1021/acs.jpclett.8b01326
C.-H. Chen, D. S. Krylov, S. M. Avdoshenko, F. Liu, L. Spree, R. Westerström, C. Bulbucan, M. Studniarek, J. Dreiser, A. U. B. Wolter, B. Büchner, A. A. Popov. Magnetic hysteresis in self-assembled monolayers of Dy-fullerene single molecule magnets on gold. Nanoscale 2018, 10, 11287-11292. DOI: 10.1039/C8NR00511G
I. V. Kuvychko, T. T. Clikeman, C. Dubceac, Y.-S. Chen, M. Petrukhina, S. H. Strauss, A. A. Popov, O. V. Boltalina. Understanding Polyarene Trifluoromethylation with Hot CF3 Radicals using Corannulene. Eur. J. Org. Chem. 2018, (31), 4233-4245. DOI: 10.1002/ejoc.201800508
M. R. Ajayakumar, Y. Fu, J. Ma, F. Hennersdorf, H. Komber, J. J. Weigand, A. Alfonsov, A. A. Popov, R. Berger, J. Liu, K. Müllen, X. Feng. Toward Full Zigzag-Edged Nanographenes: peri-Tetracene and Its Corresponding Circumanthracene. J. Am. Chem. Soc. 2018, 140 (20), 6240–6244. DOI: 10.1021/jacs.8b03711
D. S. Krylov, F. Liu, A. Brandendurg, L. Spree, V. Bon, S. Kaskel, A. U. B. Wolter, B. Büchner, S. M. Avdoshenko, A. A. Popov. Magnetization relaxation in the single-ion magnet DySc2N@C80: quantum tunneling, magnetic dilution, and unconventional temperature dependence. Phys. Chem. Chem. Phys. 2018, 20, 11656-11672. DOI: 10.1039/C8CP01608A
G. Velkos, D. S. Krylov, K. Kirkpatrick, X. Liu, L. Spree, A. U. B. Wolter, B. Büchner, H. C. Dorn, A. A. Popov. Giant exchange coupling and field-induced slow relaxation of magnetization in Gd2@C79N with a single-electron Gd–Gd bond. Chem. Commun. 2018, 54, 2902-2905. DOI: 10.1039/C8CC00112J
B. J. Eleazer, M. D. Smith, A. A. Popov, D. V. Peryshkov. Expansion of the (BB)>Ru metallacycle with coinage metal cations: formation of B–M–Ru–B (M = Cu, Ag, Au) dimetalacyclodiboryls. Chem. Sci. 2018, 9, 2601-2608. DOI: 10.1039/C8SC00190A
L. K. San, S. N. Spisak, C. Dubceac, S. H M. Deng, I. V. Kuvychko, M. A. Petrukhina, X.-B. Wang, A. A. Popov, S. H. Strauss, O. V. Boltalina. Experimental and DFT Studies of the Electron-Withdrawing Ability of Perfluoroalkyl (RF) Groups: Electron Affinities of PAH(RF)n Increase Significantly with Increasing RF Chain Length. Chem. Eur. J. 2018, 24 (6), 1441-1447. DOI: 10.1002/chem.201704868
A. A. Popov. Redox-active metal–metal bonds between lanthanides in dimetallofullerenes. Curr. Opin. Electrochem. 2018, 8, 73-80. DOI: 10.1016/j.coelec.2017.12.003
M. Zalibera, D. S. Krylov, D. Karagiannis, P.-A. Will, F. Ziegs, S. Schiemenz, W. Lubitz, S. Reineke, A. Savitsky, A. A. Popov. Thermally-activated delayed fluorescence in Y3N@C80 endohedral fullerene: time resolved luminescence and electron paramagnetic resonance studies. Angew. Chem. Int. Ed. 2018, 130 (1), 283–287. DOI: 10.1002/anie.201710637
F. Liu, S. Wang, C.-L. Gao, Q. Deng, X. Zhu, A. Kostanyan, R. Westerström, F. Jin, S.-Y. Xie, A. A. Popov, T. Greber, S. Yang. Mononuclear Clusterfullerene Single-Molecule Magnet Containing Strained Fused-Pentagons Stabilized by a Nearly Linear Metal Cyanide Cluster. Angew. Chem. Int. Ed. 2017, 56 (7), 1830-1834. DOI: 10.1002/anie.201611345.
A. M. Rice, W. B. Fellows, E. A. Dolgopolova, A. B. Greytak, A. K. Vannucci, M. D. Smith, S. G. Karakalos, J. A. Krause, S. M. Avdoshenko, A. A. Popov, N. B. Shustova. Hierarchical Corannulene-Based Materials: Energy Transfer and Solid-State Photophysics. Angew. Chem. Int. Ed. 2017, 56 (16), 4525-4529. DOI: 10.1002/anie.201612199
M. Richter, K. S. Schellhammer, P. Machata, G. Cuniberti, A. A. Popov, F. Ortmann, R. F. J. Berger, K. Müllen, X. Feng. Polycyclic Heteroaromatic Hydrocarbons Containing a Benzoisoindole Core. Org. Chem. Front. 2017, 4, 847-852. DOI: 10.1039/C7QO00180K
F. Liu, F. Jin, S. Wang, A. A. Popov, S. Yang. Pyramidal TiTb2C cluster encapsulated within the popular Ih(7)-C80 fullerene cage. Inorg. Chim. Acta 2017, 468, 203-208. DOI: 10.1016/j.ica.2017.04.027
N. A. Samoylova, S. M. Avdoshenko, D. S. Krylov, H. R Thompson, A. Kirkhorn, M. Rosenkranz, S. Schiemenz, F. Ziegs, A. U. B. Wolter, S. Yang, S. Stevenson, A. A. Popov. Confining the spin between two metal atoms within the carbon cage: Redox-active metal-metal bonds in dimetallofullerenes and their stable cation radicals. Nanoscale 2017, 9, 7977-7990. DOI: 10.1039/C7NR02288C
S. Schimmel, Z. Sun, D. Baumann, D. Krylov, N. Samoylova, A. Popov, B. Büchner, C. Hess. Adsorption characteristics of Er3N@C80 on W(110) and Au(111) studied via STM/STS. Beilstein J. Nanotechnol. 2017, 8, 1127-1134. DOI: 10.3762/bjnano.8.114
J. Liu, J. Ma, K. Zhang, P. Ravat, P. Machata, S. M. Avdoshenko, F. Hennersdorf, H. Komber, W. Pisula, J. J. Weigand, A. A. Popov, R. Berger, K. Müllen, X. Feng. π-Extended and Curved Anti-Aromatic Polycyclic Hydrocarbons. J. Am. Chem. Soc. 2017, 139 (22), 7513-7521. DOI: 10.1021/jacs.7b01619
B. J. Eleazer, M. D. Smith, A. A. Popov, D. V. Peryshkov. Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface. Chem. Sci. 2017, 8, 5399-5407. DOI: 10.1039/C7SC01846K
D. S. Krylov, F. Liu, S. M. Avdoshenko, L. Spree, B. Weise, A. Waske, A. U. B. Wolter, B. Büchner, A. A Popov. Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih. Chem. Commun. 2017, 53, 7901-7904. DOI: 10.1039/C7CC03580B
C.-H. Chen, D. S. Krylov, S. M. Avdoshenko, F. Liu, L. Spree, R. Yadav, A. Alvertis, L. Hozoi, K. Nenkov, A. Kostanyan, T. Greber, A. U. B. Wolter, A. A. Popov. Selective arc-discharge synthesis of Dy2S-clusterfullerenes and their isomer-dependent single molecule magnetism. Chem. Sci. 2017, 8, 6451-6465. DOI: 10.1039/C7SC02395B
F. Liu, D. S. Krylov, L. Spree, S. M. Avdoshenko, N. A. Samoylova, M. Rosenkranz, A. Kostanyan, T. Greber, A. U. B. Wolter, B. Büchner, A. A. Popov. Single molecule magnet with an unpaired electron trapped between two lanthanide ions inside a fullerene. Nat. Commun. 2017, 8, 16098. DOI: 10.1038/ncomms16098
K. Łępicka, P. Pieta, A. Shkurenko, P. Borowicz, M. Majewska, M. Rosenkranz, S. Avdoshenko, A. A. Popov, W. Kutner. Spectroelectrochemical Approaches to Mechanistic Aspects of Charge Transport in meso Nickel (II) Schiff Base Electrochromic Polymer. J. Phys. Chem. C 2017, 121 (31), 16710-16720. DOI: 10.1021/acs.jpcc.7b04700
F. Fritz, R. Westerström, A. Kostanyan, C. Schlesier, J. Dreiser, B. Watts, L. Houben, M. Luysberg, S. M Avdoshenko, A. A. Popov, C. M. Schneider, C. Meyer. Nanoscale X-ray investigation of magnetic metallofullerene peapods. Nanotechnology 2017, 28, 435703. DOI: 10.1088/1361-6528/aa8b4c
K. Xu, Y. Fu, Y. Zhou, F. Hennersdorf, P. Machata, I. Vincon, J. J. Weigand, A. A. Popov, R. Berger, X. Feng. Cationic Nitrogen Doped Helical Nanographenes. Angew. Chem. Int. Ed. 2017, 56 (50), 15876-15881. DOI: 10.1002/anie.201707714
A. Mansikkamäki, A.A. Popov, Q. Deng, N. Iwahara, L. F. Chibotaru. Interplay of spin-dependent delocalization and magnetic anisotropy in the ground and excited states of [Gd2@C78]− and [Gd2@C80]−. J. Chem. Phys. 2017, 147 (12), 124305. DOI: 10.1063/1.5004183
A. Kostanyan, R. Westerström, Y. Zhang, D. Kunhardt, R. Stania, B. Büchner, A. A. Popov, T. Greber. Switching molecular conformation with the torque on a single magnetic moment. Phys. Rev. Lett. 2017, 119 (23), 237202. DOI: 10.1103/PhysRevLett.119.237202
K. C. Rippy, E. V. Bukovsky, T. T. Clikeman, Y.-S. Chen, G.-L. Hou, X.-B. Wang, A. A. Popov, O. V. Boltalina, S. H. Strauss. Copper Causes Regiospecific Formation of C4F8-Containing Six-Membered Rings and their Defluorination/Aromatization to C4F4-Containing Rings in Triphenylene/1,4-C4F8I2 Reactions. Chem. Eur. J. 2016, 22 (3), 874-877. DOI: 10.1002/chem.201504291
Q. Deng, T. Heine, S. Irle, A. A. Popov. Self-Assembly of Endohedral Metallofullerenes: A Decisive Role of Cooling Gas and Metal-Carbon Bonding. Nanoscale 2016, 8, 3796-3808. DOI: 10.1039/C5NR08645K
E. V. Bukovsky, B. W. Larson, T. T. Clikeman, Y.-S. Chen, A. A. Popov, O. V. Boltalina, S. H. Strauss. Structures and structure-related electronic properties of new C60(CF3)10 isomers. J. Fluor. Chem. 2016, 185, 103-117. DOI: 10.1016/j.jfluchem.2016.02.007
K. Junghans, M. Rosenkranz, A. A. Popov. Sc3CH@C80: selective 13C enrichment of the central carbon atom. Chem. Commun. 2016, 52, 6561-6564. DOI: 10.1039/C5CC10025A
D. E. Williams, E. A. Dolgopolova, D. C. Godfrey, E. D. Ermolaeva, P. J. Pellechia, A. B. Greytak, M. D. Smith, S. M. Avdoshenko, A. A. Popov, N. B. Shustova. Fulleretic Well-Defined Scaffolds: Donor–Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics. Angew. Chem. Int. Ed. 2016, 55 (31), 9070-9074. DOI: 10.1002/anie.201603584
K. Junghans, K. B. Ghiassi, N. A. Samoylova, Q. Deng, M. Rosenkranz, M. M. Olmstead, A. L. Balch, A. A. Popov. Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes – Sc2TiC@Ih-C80, Sc2TiC@D5h-C80, and Sc2TiC2@Ih-C80: Metal Size Tuning of the TiIV/TiIII Redox Potentials. Chem. Eur. J. 2016, 22 (37), 13098–13107. DOI: 10.1002/chem.201601655
D. V. Konarev, L. Zorina, S. S. Khasanov, A. A Popov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya. Crystalline anionic complex of scandium nitride endometallo-fullerene: Experimental observation of single-bonded (Sc3N@Ih-C80−)2 dimers. Chem. Commun. 2016, 52, 10763-10766. DOI: 10.1039/C6CC05550H
B. J. Eleazer, M. D. Smith, A. A. Popov, D. V. Peryshkov. (BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center. J. Am. Chem. Soc. 2016, 138 (33), 10531-10538. DOI: 10.1021/jacs.6b05172
X. Wang, F. Zhang, K. S. Schellhammer, P. Machata, F. Ortmann, G. Cuniberti, Y. Fu, J. Hunger, R. Tang, A. A. Popov, R. Berger, K. Müllen, X. Feng. Synthesis of NBN-type Zigzag-Edged Polycyclic Aromatic Hydrocarbons: 1,9-Diaza-9a-boraphenalene as a Structural Motif. J. Am. Chem. Soc. 2016, 138(36), 11606-11615. DOI: 10.1021/jacs.6b05172
B. W. Larson, O. G. Reid, D. C. Coffey, S. M. Avdoshenko, A. A. Popov, O. V. Boltalina, S. H. Strauss, N. Kopidakis, G. Rumbles. Inter-Fullerene Electronic Coupling Controls the Efficiency of Photoinduced Charge Generation in Organic Bulk Heterojunctions. Adv. Energy Mater. 2016, 6 (24), 1601427. DOI: 10.1002/aenm.201601427.
F. Liu, C.-L. Gao, Q. Deng, X. Zhu, A. Kostanyan, R. Westerström, S. Wang, Y.-Z. Tan, J. Tao, S.-Y. Xie, A. A. Popov, T. Greber, S. Yang. Triangular Monometallic Cyanide Cluster Entrapped in Carbon Cage with Geometry-Dependent Molecular Magnetism. J. Am. Chem. Soc. 2016, 138, 14764-14771. DOI: 10.1021/jacs.6b09329.
A. Konkin, A. Popov, U. Ritter, S. Orlinskii, G. Mamin, A. Aganov, A. A. Konkin, P. Scharff. Combined W-Band Light-Induced ESR/ENDOR/TRIPLE and DFT Study of PPVtype/PC61BM Ion Radicals. J. Phys. Chem. C 2016, 120 (51), 28905-28911. DOI: 10.1021/acs.jpcc.6b08034
Y. Zhang, K. B. Ghiassi, Q. Deng, N. Samoylova, M. M. Olmstead, A. L. Balch, A. A. Popov. Synthesis and Structure of LaSc2N@Cs(hept)‐C80 with One Heptagon and Thirteen Pentagons. Angew. Chem. Int. Ed. 2015, 54 (2), 495-499. DOI: 10.1002/anie.201409094
T. T. Clikeman, S. H. M. Deng, A. A Popov, X.-B. Wang, S. H. Strauss, O. V. Boltalina. Fullerene cyanation does not always increase electron affinity: an experimental and theoretical study. Phys. Chem. Chem. Phys. 2015, 7, 551-556. DOI: 10.1039/C4CP04287E
L. K San, E. V. Bukovsky, B. W. Larson, J. B. Whitaker, S. Deng, N. Kopidakis, G. Rumbles, A. A Popov, Y.-S. Chen, X.-B. Wang, O. V. Boltalina, S. H Strauss. A faux hawk fullerene with PCBM-like properties. Chem. Sci. 2015, 6, 1801-1815. DOI: 10.1039/C4SC02970D
Q. Deng, K. Junghans, A. A. Popov. Carbide clusterfullerenes with odd number of carbon atoms: molecular and electronic structures of Sc4C@C80, Sc4C@C82, and Sc4C3@C80. Theor. Chem. Acc. 2015, 134, 10. DOI: 10.1007/s00214-014-1610-6
R. Westerström, A.-C. Uldry, R. Stania, J. Dreiser, C. Piamonteze, M. Muntwiler, F. Matsui, S. Rusponi, H. Brune, S. Yang, A. Popov, B. Büchner, B. Delley, T. Greber. Surface aligned magnetic moments and hysteresis of an endohedral single-molecule magnet on a metal. Phys. Rev. Lett. 2015, 114, 087201. DOI: 10.1103/PhysRevLett.114.087201
O. V. Boltalina, A. A. Popov, I. V. Kuvychko, N. B. Shustova, S. H. Straus. Perfluoroalkylfullerenes. Chem. Rev. 2015, 115, 1051-1105. DOI: 10.1021/cr5002595
Y. Zhang, D. Krylov, M. Rosenkranz, S. Schiemenz, A. A. Popov. Magnetic Anisotropy of Endohedral Lanthanide Ions: Paramagnetic NMR Study of MSc2N@C80-Ih with M running through the Whole 4f Row. Chem. Sci. 2015, 6, 2328-2341. DOI: 10.1039/C5SC00154D
Q. Deng, A. A. Popov. Prato and Bingel-Hirsch cycloaddition to heptagon-containing LaSc2N@Cs(hept)-C80: importance of pentalene unit. Chem. Commun. 2015, 51, 5637-5640. DOI: 10.1039/C5CC00296F
T. Wei, F. Liu, S. Wang, X. Zhu, A. A. Popov, S. Yang. An Expanded Family of Dysprosium–Scandium Mixed-Metal Nitride Clusterfullerenes: The Role of Lanthanide Metal on the Carbon Cage Size Distribution. Chem. Eur. J. 2015, 21, 5750-5759. DOI: 10.1002/chem.201406265
U. Pfaff, A. Hildebrandt, M. Korb, D. Schaarschmidt, M. Rosenkranz, A. Popov, H. Lang. Five-Membered Heterocycles as Linking Units in Strongly Coupled Homobimetallic Group 8 Metal Half-Sandwich Complexes. Organometallics 2015, 34, 2826-2840. DOI: 10.1021/acs.organomet.5b00104
L. K. San, T. T. Clikeman, C. Dubceac, A. A. Popov, Y.-S. Chen, M. A. Petrukhina, S. H. Strauss, O. V. Boltalina. Corannulene Molecular Rotor with Flexible Perfluorobenzyl Blades: Synthesis, Structure and Properties. Chem. Eur. J. 2015, 21, 9488–9492. DOI: 10.1002/chem.201500465
K. Junghans, C. Schlesier, A. Kostanyan, N. A. Samoylova, Q. Deng, M. Rosenkranz, S. Schiemenz, R. Westerström, T. Greber, B. Büchner, A. A. Popov. Methane as a selectivity booster in the synthesis of endohedral fullerenes: towards selective synthesis of the single molecule magnet Dy2TiC@C80 and its congener Dy2TiC2@C80. Angew. Chem. Int. Ed. 2015, 54 (45), 13411-13415. DOI: 10.1002/anie.201505870.
M. Zalibera, P. Machata, T. T. Clikeman, M. Rosenkranz, S. H. Strauss, O. V. Boltalina, A. A. Popov. 19F NMR-, ESR-, and vis-NIR-spectroelectrochemical study of the unconventional reduction behaviour of perfluoroalkylated fullerene: dimerization of the C70(CF3)10− radical anion. Analyst 2015, 140, 7209-7216. DOI: 10.1039/C5AN01129A
Y. Zhang, A. A. Popov, L. Dunsch. Endohedral Metal or a Fullerene Cage Based Oxidation? Redox Duality of Nitride Clusterfullerenes CexM3−xN@C78–88 (x = 1, 2; M = Sc and Y) Dictated by the Encaged Metals and the Carbon Cage Size. Nanoscale 2014, 6, 1038-1048. DOI: 10.1039/C3NR05433K
A. A. Popov, C. Kästner, M. Krause, L. Dunsch. Carbon Cage Vibrations of M@C82 and M2@C2n (M = La, Ce; 2n = 72, 78, 80): The Role of the Metal Atoms. Fullerenes Nanotubes Carbon Nanostruct. 2014, 22 (1-3), 202-214. DOI: 10.1080/1536383X.2013.798729
R. Westerström, J. Dreiser, C. Piamonteze, M. Muntwiler, S. Weyeneth, K. Krämer, S.-X. Liu, S. Decurtins, A. Popov, S. Yang, L. Dunsch, T. Greber. Tunneling, remanence, and frustration in dysprosium-based endohedral single-molecule magnets. Phys. Rev. B 2014, 89, 060406. DOI: 10.1103/PhysRevB.89.060406
J. Zhao, Q. Deng, A. Bachmatiuk, G. Sandeep, A. Popov, J. Eckert, M. H. Rümmeli. Free-Standing Single-Atom-Thick Iron Membranes Suspended in Graphene Pores. Science 2014, 343 (6176), 1228-1232. DOI: 10.1126/science.1245273
Q. Deng, A. A. Popov. Clusters encapsulated in Endohedral Metallofullerenes: How strained are they? J. Am. Chem. Soc. 2014, 136 (11), 4257-4264. DOI: 10.1021/ja4122582
A. Svitova, Y. Krupskaya, N. Samoylova, R. Kraus, J. Geck, L. Dunsch, A. A. Popov. Magnetic moments and exchange coupling in nitride clusterfullerenes GdxSc3–xN@C80 (x = 1–3). Dalton Trans. 2014, 43, 7387-7390. DOI: 10.1039/C3DT53367K
L. K. San, E. V. Bukovsky, I. V. Kuvychko, A. A. Popov, S. H. Strauss, O. V. Boltalina. Single-Step Gas-Phase Polyperfluoroalkylation of Naphthalene Leads to Thermodynamic Products. Chem. Eur. J. 2014, 20 (15), 4373-4379. DOI: 10.1002/chem.201304554
B. W. Larson, J. B. Whitaker, A. A. Popov, N. Kopidakis, G. Rumbles, O. V. Boltalina, S. H. Strauss. Thermal [6,6] → [6,6] Isomerization and Decomposition of PCBM (Phenyl-C61-Butyric Acid Methyl Ester). Chem. Mater. 2014, 26 (7), 2361-2367. DOI: 10.1021/cm500594u
A. L. Svitova, K. B. Ghiassi, C. Schlesier, K. Junghans, Y. Zhang, M. M. Olmstead, A. L. Balch, L. Dunsch, A. A. Popov. Endohedral fullerene with μ3-carbido ligand and Titanium-Carbon double bond stabilized inside a carbon cage. Nat. Commun. 2014, 5, 3568. DOI: 10.1038/ncomms4568
Y. Zhang, A. A. Popov. Transition-Metal and Rare-Earth-Metal Redox Couples inside Carbon Cages: Fullerenes Acting as Innocent Ligands. Organometallics 2014, 33 (18), 4537-4549. DOI: 10.1021/om5000387
J. Dreiser, R. Westerström, C. Piamonteze, F. Nolting, S. Rusponi, H. Brune, S. Yang, A. A. Popov, L. Dunsch, T. Greber. X-ray induced demagnetization of single-molecule magnets. Appl. Phys. Lett. 2014, 105 (3), 032411. DOI: 10.1063/1.4891485
Y. Zhang, D. Krylov, S. Schiemenz, M. Rosenkranz, R. Westerström, J. Dreiser, T. Greber, B. Büchner, A. A. Popov. Cluster-size dependent internal dynamics and magnetic anisotropy of Ho ions in HoM2N@C80 and Ho2MN@C80 families (M = Sc, Lu, Y). Nanoscale 2014, 6 (19), 11431-11438. DOI: 10.1039/C4NR02864C
J. Dreiser, R. Westerström, Y. Zhang, A. A. Popov, L. Dunsch, K. Krämer, S.-X. Liu, S. Decurtins, T. Greber. The Metallofullerene Field-Induced Single-Ion Magnet HoSc2N@C80. Chem. Eur. J. 2014, 20 (42), 13536-13540. DOI: 10.1002/chem.201403042
A. A. Popov, A. D. Pykhova, I. N. Ioffe, F.-F. Li, L. Echegoyen. Anion radicals of isomeric [5,6] and [6,6] benzoadducts of Sc3N@C80: remarkable differences in endohedral cluster spin density and dynamics. J. Am. Chem. Soc. 2014, 136 (38), 13435-13441. DOI: 10.1021/ja507607k
B. Elliott, A. D. Pykhova, J. Rivera, C. Cardona, L. Dunsch, A. A. Popov, L. Echegoyen. Spin Density and Cluster Dynamics in Sc3N@C80− upon [5,6] Exohedral Functionalization: An ESR and DFT Study. J. Phys. Chem. C 2013, 117 (5), 2344-2348. DOI: 10.1021/jp310024u
T. T. Clikeman, I. V. Kuvychko, N. B. Shustova, Y.-S. Chen, A. A. Popov, O. V. Boltalina, S. H. Strauss. Regioselective Sequential Additions of Nucleophiles and Electrophiles to Perfluoroalkylfullerenes: Which Cage C Atoms Are the Most Reactive and Why. Chem. Eur. J. 2013, 19 (16), 5070-5080. DOI: 10.1002/chem.201203571
A. Svitova, A. A. Popov, L. Dunsch. Gd/Sc-based Mixed Metal Nitride Cluster Fullerenes: The Mutual Influence of the Cage and Cluster Size and the Role of Sc in the Electronic Structure. Inorg. Chem. 2013, 52 (6), 3368-3380. DOI: 10.1021/ic400049k
S. M. Avdoshenko, P. Koskinen, H. Sebincli, A. A. Popov, C. G. Rocha. Topological Signatures in the Electronic Structure of Graphene Spirals. Sci. Rep. 2013, 3, 1632. DOI: 10.1038/srep01632
A. A. Popov, S. Yang, L. Dunsch. Endohedral Fullerenes. Chem. Rev. 2013, 113 (8), 5989–6113. DOI: 10.1021/cr300297r
I. V. Kuvychko, C. Dubceac, S. H. M. Deng, X. B. Wang, A. A. Granovsky, A. A. Popov, M. A. Petrukhina, S. H. Strauss, O. V. Boltalina. C20H4(C4F8)3: A Fluorine-Containing Annulated Corannulene that Is a Better Electron Acceptor Than C60. Angew. Chem. Int. Ed. 2013, 52 (29), 7505-7508. DOI: 10.1002/anie.201300796
B. W. Larson, J. B. Whitaker, A. A. Popov, X.-B. Wang, G. Rumbles, N. Kopidakis, S. H. Strauss, O. V. Boltalina. Electron Affinity of Phenyl-C61-Butyric Acid Methyl Ester (PC61BM). J. Phys. Chem. C 2013, 117 (29), 14958-14964. DOI: 10.1021/jp403312g
Y. Zhang, S. Schiemenz, A. A. Popov, L. Dunsch. Strain-Driven Endohedral Redox Couple CeIV/CeIII in Nitride Clusterfullerenes CeM2N@C80 (M = Sc, Y, Lu). J. Phys. Chem. Lett. 2013, 4, 2404-2409. DOI: 10.1021/jz4009773
K. P. Castro, Y. Jin, J. J. Rack, S. H. Strauss, O. V. Boltalina, A. A. Popov. Perfluoroalkyl [70]-Fullerenes as Robust Highly-Luminescent Fluorocarbons, or Position of One CF3 Group Matters! J. Phys. Chem. Lett. 2013, 4, 2500-2507. DOI: 10.1021/jz401068t
T. T. Clikeman, S. H. M. Deng, S. Avdoshenko, X.-B. Wang, A. A. Popov, S. H. Strauss, O. V. Boltalina. Fullerene “Superhalogen” Radicals: the Substituent Effect on Electronic Properties of 1,7,11,24,27-C60X5. Chem. Eur. J. 2013, 19 (45), 15404-15409. DOI: 10.1002/chem.201301234
E. V. Bukovsky, S. R. Fiedler, D. V. Peryshkov, A. A. Popov, O. P. Anderson, S. H. Strauss. The Structure of (H3O)2B12F12.6H2O, a CCP Lattice of B12F122− Anions Intercalated with a Non-Planar Moguled Network of O–H...O Connected O6 Rings. Eur. J. Inorg. Chem. 2012, (2), 208-212. DOI: 10.1002/ejic.201101118
C. Chen, F. Liu, S. Li, N. Wang, A. A. Popov, M. Jiao, T. Wei, Q. Li, L. Dunsch, S. Yang. Titanium/Yttrium Mixed Metal Nitride Clusterfullerene TiY2N@C80: Synthesis, Isolation, and Effect of the Group-III Metal. Inorg. Chem. 2012, 51 (5), 3039–3045. DOI: 10.1021/ic202354u
I. Kuvychko, J. Whitaker, B. Larson, T. Folsom, N. B. Shustova, S. Avdoshenko, Y.-S. Chen, H. Wen, X.-B. Wang, L. Dunsch, A. A. Popov, S. H. Strauss, O. V. Boltalina. Substituent effects in a series of 1,7-C60(RF)2 compounds (RF = CF3, C2F5, n-C3F7, i-C3F7, n-C4F9, s-C4F9, n-C8F17): electron affinities, reduction potentials and E(LUMO) values are not always correlated. Chem. Sci. 2012, 3 (5), 1399-1407. DOI: 10.1039/C2SC01133F
I. V. Kuvychko, S. N. Spisak, Y.-S. Chen, A. A. Popov, M. A. Petrukhina, S. H. Strauss, O. V. Boltalina. A Buckybowl with a Lot of Potential: C5-C20H5(CF3)5. Angew. Chem. Int. Ed. 2012, 51 (20), 4939–4942. DOI: 10.1002/anie.201200178
R. Westerström, J. Dreiser, C. Piamonteze, M. Muntwiler, S. Weyeneth, H. P. Brune, S. Rusponi, F. Nolting, A. A Popov, S. Yang, L. Dunsch, T. Greber. An endohedral single-molecule magnet with long relaxation times: DySc2N@C80. J. Am. Chem. Soc. 2012, 134 (24), 9840–9843. DOI: 10.1021/ja301044p
Y. Zhang, A. A. Popov, S. Schiemenz, L. Dunsch. Synthesis, Isolation and Spectroscopic Characterization of Holmium-Based Mixed-Metal Nitride Clusterfullerenes: HoxSc3−xN@C80 (x=1, 2). Chem. Eur. J. 2012, 18 (31), 9691-9698. DOI: 10.1002/chem.201200574
A. A. Popov, S. M. Avdoshenko, A. M. Pendás, L. Dunsch. Bonding between strongly repulsive metal atoms: an oxymoron made real in a confined space of endohedral metallofullerenes. Chem. Commun. 2012, 48, 8031-8050. DOI: 10.1039/C2CC32568C
A. A. Popov, N. Chen, J. R. Pinzón, S. Stevenson, L. A. Echegoyen, L. Dunsch. A redox-active scandium-oxide cluster inside a fullerene cage: Spectroscopic, voltammetric, ESR spectroelectrochemical and extended DFT study of Sc4O2@C80 and its ion-radicals. J. Am. Chem. Soc. 2012, 134 (48), 19607–19618. DOI: 10.1021/ja306728p
T. Huang, J. Zhao, M. Feng, A. A. Popov, S. Yang, L. Dunsch, H. Petek. A multi-state single-molecule switch actuated by rotation of an encapsulated cluster within a fullerene cage. Chem. Phys. Lett. 2012, 552, 1-12. DOI: 10.1016/j.cplett.2012.09.064
A. Svitova, K. Braun, A. A. Popov, L. Dunsch. A Platform for Specific Delivery of Lanthanide–Scandium Mixed-Metal Cluster Fullerenes into Target Cells. Chem. Open 2012, 1 (5), 207-210. DOI: 10.1002/open.201200023
I. Ibrahim, A. Bachmatiuk, D. Grimm, A. Popov, S. Makharza, M. Knupfer, B. Büchner, G. Cuniberti, M. H. Rümmeli. Understanding high yield catalyst-free growth of horizontally aligned single walled carbon nanotubes nucleated by activated C60 species. ACS Nano 2012, 6 (12), 10825-10834. DOI: 10.1021/nn304189y
N. B. Shustova, I. V. Kuvychko, D. V. Peryshkov, J. B. Whitaker, B. W. Larson, Y.-S. Chen, L. Dunsch, K. Seppelt, A. A. Popov, S. H. Strauss, O. V. Boltalina. Chemical tailoring of fullerene acceptors: synthesis, structures and electrochemical properties of perfluoroisopropylfullerenes. Chem. Commun. 2011, 47, 875-877. DOI: 10.1039/C0CC03247F
N. B. Shustova, D. V. Peryshkov, I. V. Kuvychko, Y.-S. Chen, M. A. Mackey, C. E. Coumbe, D. T. Heaps, B. S. Confait, T. Heine, J. P. Phillips, S. Stevenson, L. Dunsch, A. A. Popov, S. H. Strauss, O. V. Boltalina. Poly(perfluoroalkylation) of Metallic Nitride Fullerenes Reveals Addition-Pattern Guidelines: Synthesis and Characterization of a Family of Sc3N@C80(CF3)n (n = 2−16) and Their Radical Anions. J. Am. Chem. Soc. 2011, 133 (8), 2672–2690. DOI: 10.1021/ja109462j
A. A. Popov, L. Dunsch. Electrochemistry in Cavea: Endohedral Redox Reactions of Encaged Species in Fullerenes. J. Phys. Chem. Lett. 2011, 2 (7), 786-794. DOI: 10.1021/jz200063k
A. A. Popov, L. Dunsch. Charge controlled changes in the cluster and spin dynamics of Sc3N@C80(CF3)2: the flexible spin density distribution and its impact on ESR spectra. Phys. Chem. Chem. Phys. 2011, 13 (19), 8977-8984. DOI: 10.1039/C0CP02070B
N. B. Shustova, I. V. Kuvychko, A. A. Popov, M. von Delius, L. Dunsch, O. P. Anderson, A. Hirsch, S. H. Strauss, O. V. Boltalina. Nitrogen Directs Multiple Radical Additions to the 9,9′-Bi-1-aza(C60-Ih)[5,6]fullerene: X-ray Structure of 6,9,12,15,18-C59N(CF3)5. Angew. Chem. Int. Ed. 2011, 50 (24), 5537-5540. DOI: 10.1002/anie.201101227
A. A. Popov, S. M. Avdoshenko, G. Cuniberti, L. Dunsch. Dimerization of Radical-Anions: Nitride Clusterfullerenes vs Empty Fullerenes. J. Phys. Chem. Lett. 2011, 2, 1592-1600. DOI: 10.1021/jz200586v
I. V. Kuvychko, N. B. Shustova, S. M. Avdoshenko, A. A. Popov, S. H. Strauss, O. V. Boltalina. In Search of Fullerene-Based Superacids: Synthesis, X-ray structure and DFT study of C60(C2F5)5H. Chem. Eur. J. 2011, 17, 8799-8802. DOI: 10.1002/chem.201101328
A. A. Popov, S. Schiemenz, S. M. Avdoshenko, S. Yang, G. Cuniberti, L. Dunsch. The State of Asymmetric Nitride Clusters in Endohedral Fullerenes as Studied by 14N-NMR Spectroscopy: Experiment and Theory. J. Phys. Chem. C 2011, 115, 15257–15265. DOI: 10.1021/jp204290f
A. A. Popov, S. Jeon, V. M. Senyavin, L. Dunsch, S. Maragani, M. Wang, L.-S. Tan, L. Y. Chian. Unique Ultralow 18π-Trannulenyl HOMO–LUMO Energy Gap of Photostable Emerald-Green D3d-2-Methylmalonato[60]fullerenes. J. Phys. Chem. Lett. 2011, 2, 2296–2299. DOI: 10.1021/jz200978f
I. Ibrahim, A. Bachmatiuk, M. H. Rümmeli, U. Wolff, A. Popov, O. Boltalina, B. Büchner, G. Cuniberti. Growth of catalyst-assisted and catalyst-free horizontally aligned single wall carbon nanotubes. phys. stat. solidi (b) 2011, 248 (11), 2467–2470. DOI: 10.1002/pssb.201100073
S. M. Avdoshenko, I. N. Ioffe, G. Cuniberti, L. Dunsch, A. Popov. Organometallic Complexes of Graphene: Towards Atomic Spintronics Using Graphene Web. ACS Nano 2011, 5(12), 9939-9949. DOI: 10.1021/nn203719a
T. Huang, J. Zhao, M. Feng, A. A. Popov, S. Yang, L. Dunsch, H. Petek. A molecular switch based on current-driven rotation of an encapsulated cluster within a fullerene cage. Nano Lett. 2011, 11, 5327-5332. DOI: 10.1021/nl2028409
N. B. Shustova, Z. Mazej, Y.-S. Chen, A. A. Popov, S. H. Strauss, O. V. Boltalina. Saturnene Revealed: X-ray Crystal Structure of D5d-C60F20 Formed in Reactions of C60 with AxMFy Fluorinating Agents (A=Alkali Metal; M=3d Metal). Angew. Chem. Int. Ed. 2010, 49, 812-815. DOI: 10.1002/anie.200905832
X.-B. Wang, C. Chi, I. V. Kuvychko, K. Seppelt, A. A. Popov, S. H. Strauss, O. V. Boltalina, L.-S. Wang. Photoelectron Spectroscopy of C60Fn– and C60Fm2– (n = 17, 33, 35, 43, 45, 47; m = 34, 46) in the Gas Phase and the Generation and Characterization of C1-C60F47– and D2-C60F44 in Solution. J. Phys. Chem. A 2010, 114, 1756-1765. DOI: 10.1021/jp9097364
A. A. Popov, L. Zhang, L. Dunsch. A pseudoatom in a cage: trimetallofullerene Y3@C80 mimics Y3N@C80 with nitrogen substituted by a pseudoatom. ACS Nano 2010, 4(2), 795-802. DOI: 10.1021/nn901422z
L. Dunsch, S. Yang, L. Zhang, A. Svitova, S. Oswald, A. A. Popov. Metal Sulfide in a C82 Fullerene Cage: A New Form of Endohedral Clusterfullerenes. J. Am. Chem. Soc. 2010, 132, 5413-5421. DOI: 10.1021/ja909580j
N. Chen, S. Klod, P. Rapta, A. A. Popov, L. Dunsch. Direct Arc-Discharge Assisted Synthesis of C60H2(C3H5N): A cis-1-Pyrrolino C60 Fullerene Hydride with Unusual Redox Properties. Chem. Mater. 2010, 22 (8), 2608-2615. DOI: 10.1021/cm903870v
A. Vargová, A. A. Popov, P. Rapta, B. Sun, L. Zhang, L. Dunsch. Electrochemical Tuning of Spin States of the Endohedral Metallofullerene Y@C82 as Probed by ESR Spectroelectrochemistry. ChemPhysChem, 2010, 11, 1650-1653. DOI: 10.1002/cphc.200901015
A. A. Popov, N. B. Shustova, A. L. Svitova, M. A. Mackey, C. E. Coumbe, J. P. Phillips, S. Stevenson, S. H. Strauss, O. V. Boltalina, L. Dunsch. Redox tuning endohedral fullerene spin states. From the dication to the trianion radical of Sc3N@C80(CF3)2 in five reversible single-electron steps. Chem. Eur. J. 2010, 16 (16), 4721-4724. DOI: 10.1002/chem.201000205.
I. V. Kuvychko, A. V. Streletskii, N. B. Shustova, K. Seppelt, T. Drewello, A. A. Popov, S. H. Strauss, O. V. Boltalina. Soluble Chlorofullerenes C60Cl2,4,6,8,10. Synthesis, Purification, Compositional Analysis, Stability, and Experimental/Theoretical Structure Elucidation, Including the X-ray Structure of C1-1,2,7,10,14,24,25,28,29,31-C60Cl10. J. Am .Chem. Soc. 2010, 132 (18), 6443-6462. DOI: 10.1021/ja1005256
L. Zhang, A. A. Popov, S. Yang, S. Klod, P. Rapta, L. Dunsch. An endohedral redox system in a fullerene cage: the Ce based mixed-metal cluster fullerene Lu2CeN@C80. Phys. Chem. Chem. Phys. 2010, 12, 7840-7847. DOI: 10.1039/c002918a.
A. A. Popov, C. Chen, S. Yang, F. Lipps, L. Dunsch. The Spin-Flow Vibrational Spectroscopy of Molecules with Flexible Spin Density: Electrochemistry, ESR, Cluster and Spin Dynamics, and Bonding in TiSc2N@C80. ACS Nano 2010, 4 (8), 4857-4871. DOI: 10.1021/nn101115d
A. A. Popov, I. E. Kareev, N. B. Shustova, S. H. Strauss, O. V. Boltalina, L. Dunsch. Unraveling the Electron Spin Resonance Pattern of Nonsymmetric Radicals with 30 Fluorine Atoms: Electron Spin Resonance and Vis−Near-Infrared Spectroelectrochemistry of the Anion Radicals and Dianions of C60(CF3)2n (2n = 2–10) Derivatives and Density Functional Theory-Assisted Assignment. J. Am. Chem. Soc. 2010, 132 (33), 11709-11721. DOI: 10.1021/ja1043775
D. Peryshkov, A. A. Popov, S. H. Strauss. Latent Porosity in Potassium Dodecafluoro-closo-dodecaborate(2−). Structures and Rapid Room Temperature Interconversions of Crystalline K2B12F12, K2(H2O)2B12F12, and K2(H2O)4B12F12 in the Presence of Water Vapor. J. Am .Chem. Soc. 2010, 132 (39), 13902-13913. DOI: 10.1021/ja105522d
N. B. Shustova, I. E. Kareev, I. V. Kuvychko, J. B. Whitaker, S. F. Lebedkin, A. A. Popov, L. Dunsch, Y.-S. Chen, K. Seppelt, S. H. Strauss, O. V. Boltalina. High-temperature and photochemical syntheses of C60 and C70 fullerene derivatives with linear perfluoroalkyl chains. J. Fluor. Chem. 2010, 131, 1198-1212. DOI: 10.1016/j.jfluchem.2010.08.001
I. V. Kuvychko, A. A. Popov, A. V. Streletskii, L. C. Nye, T. Drewello, S. H. Strauss, O. V. Boltalina. Dynamic HPLC study of C70 chlorination reveals a surprisingly selective synthesis of C70Cl8. Chem. Commun. 2010, 46, 8204-8206. DOI: 10.1039/C0CC03134H
A. A. Popov, A. V. Burtsev, V. M. Senyavin, L. Dunsch, S. I. Troyanov. Spectroscopic and Theoretical Study of the Dimeric Dicationic Fullerene Complex [(C70)2]2+(Ti3Cl13)−2. J. Phys. Chem. A 2009, 113 (1), 263-272. DOI: 10.1021/jp805264q
A. A. Popov, V. M. Senyavin, V. I. Korepanov, I. V. Goldt, A. M. Lebedev, V. G. Stankevich, K. A. Menshikov, N. Yu. Svechnikov, O. V. Boltalina, I. E. Kareev, S. Kimura, O. Sidorova, K. Kanno, I. Akimoto. Vibrational, electronic, and vibronic excitations of polar C60F18 molecules: Experimental and theoretical study. Phys. Rev. B 2009, 79 (4), 045413. DOI: 10.1103/PhysRevB.79.045413
A. A. Popov. Metal-Cage Bonding, Molecular Structures and Vibrational Spectra of Endohedral Fullerenes: Bridging Experiment and Theory. J. Comput. Theor. Nanosci. 2009, 6 (2), 292-317. DOI: 10.1166/jctn.2009.1037
M. Zalibera, P. Rapta, A. A. Popov, L. Dunsch. Charged States of Four Isomers of C84 Fullerene: In Situ ESR and Vis−NIR Spectroelectrochemistry and DFT Calculations. J. Phys. Chem. C 2009, 113 (13), 5141-5149. DOI: 10.1021/jp811274g
S. Yang, A. A. Popov, C. Chen, L. Dunsch. Mixed Metal Nitride Clusterfullerenes in Cage Isomers: LuxSc3−xN@C80 (x = 1, 2) As Compared with MxSc3−xN@C80 (M = Er, Dy, Gd, Nd). J. Phys. Chem. C 2009, 113 (18), 7616-7623. DOI: 10.1021/jp9005263
A. A. Popov, S. Yang, M. Kalbac, P. Rapta, L. Dunsch. Electronic Structure of Sc3N@C68 in Neutral and Charged States: An Experimental and TD-DFT Study. In AIP Conf. Proc. 1148 Computational Methods in Science and Engineering, Advances in Computational Science, T. E. Simos and G. Maroulis (Editors), 2009, pp 712-715. DOI: 10.1063/1.3225413
A. A. Popov, L. Dunsch. Bonding in Endohedral Metallofullerenes as Studied by Quantum Theory of Atoms in Molecules. Chem. Eur. J. 2009, 15 (38), 9707-9729. DOI: 10.1002/chem.200901045
S. Yang, C. Chen, A. A. Popov, W. Zhang, F. Liu, L. Dunsch. An endohedral titanium(III) in a clusterfullerene: putting a non-group-III metal nitride into the C80-Ih fullerene cage. Chem. Commun, 2009, 6391-6393. DOI: 10.1039/B803200A
N. B. Shustova, Y.-S. Chen, M. A. Mackey, C. E. Coumbe, J. P. Phillips, S. Stevenson, A. A. Popov, O. V. Boltalina, S. H. Strauss. Sc3N@(C80-Ih(7))(CF3)14 and Sc3N@(C80-Ih(7))(CF3)16. Endohedral Metallofullerene Derivatives with Exohedral Addends on Four and Eight Triple-Hexagon Junctions. Does the Sc3N Cluster Control the Addition Pattern or Vice Versa? J. Am. Chem. Soc. 2009, 131 (48), 17630-17637. DOI: 10.1021/ja9069216
D. V. Peryshkov, A. A. Popov, S. H. Strauss. Direct Perfluorination of K2B12H12 in Acetonitrile Occurs at the Gas Bubble−Solution Interface and Is Inhibited by HF. Experimental and DFT Study of Inhibition by Protic Acids and Soft, Polarizable Anions. J. Am. Chem. Soc. 2009, 131 (51), 18393-18403. DOI: 10.1021/ja9069437
S. Yang, A. A. Popov, M. Kalbac, L. Dunsch. The Isomers of Gadolinium Scandium Nitride Clusterfullerenes GdxSc3-xN@C80 (x=1, 2) and Their Influence on Cluster Structure. Chem. Eur. J. 2008, 14 (7), 2084-2092. DOI: 10.1002/chem.200701598
A. A. Popov, N. B. Shustova, O. V. Boltalina, S. H. Strauss, L. Dunsch. ESR-Vis/NIR Spectroelectrochemical Study of C70(CF3)2−. and C70(C2F5)2−. Radical Anions. ChemPhysChem 2008, 9 (3), 431-438. DOI: 10.1002/cphc.200700708
S. Yang, A. A. Popov, L. Dunsch. Large mixed metal nitride clusters encapsulated in a small cage: the confinement of the C68-based clusterfullerenes. Chem. Commun. 2008, 2885-2887. DOI: 10.1039/B803200A
P. Rapta, A. A. Popov, S. Yang, L. Dunsch. The Charged States of Sc3N@C68: An in situ Spectroelectrochemical Study of the Radical Cation and Radical Anion of a Non-IPR Fullerene. J. Phys. Chem. A 2008, 112 (26), 5858-5865. DOI: 10.1021/jp802655f
I. E. Kareev, I. V. Kuvychko, N. B. Shustova, S. F. Lebedkin, V. P. Bubnov, O. P. Anderson, A. A. Popov, O. V. Boltalina, S. H. Strauss. C1-(C84-C2(11))(CF3)12: Trifluoromethylation Yields Structural Proof of a Minor C84 Cage and Reveals a Principle of Higher Fullerene Reactivity. Angew. Chem. Int. Ed. 2008, 47, 6204-6207. DOI: 10.1002/anie.200801777
M. Zalibera, A. A. Popov, M. Kalbac, P. Rapta, L. Dunsch. The Extended Protocol of the empty C82:3 fullerene cage: Isolation, Structure, Spectroscopy, Electrochemistry, Spectroelectrochemistry and DFT Calculations. Chem. Eur. J. 2008, 14 (32), 9960-9967. DOI: 10.1002/chem.200800591
S. Yang, A. A. Popov, L. Dunsch. Carbon Pyramidalization in Fullerene Cages Induced by the Endohedral Cluster: the First Non-Scandium Mixed Metal Nitride Clusterfullerenes. Angew. Chem. Int. Ed. 2008, 47, 8196-8200. DOI: 10.1002/anie.200802009
I. E. Kareev, A. A. Popov, I. V. Kuvychko, N. B. Shustova, S. F. Lebedkin, V. P. Bubnov, O. P. Anderson, K. Seppelt, S. H. Strauss, O. V. Boltalina. Synthesis and X-ray or NMR/DFT Structure Elucidation of Twenty-One New Trifluoromethyl Derivatives of Soluble Cage Isomers of C76, C78, C84, and C90. J. Am. Chem. Soc. 2008, 130, 13471-13489. DOI: 10.1021/ja8041614
A. A. Popov, L. Dunsch. Hindered Cluster Rotation and 45Sc Hyperfine Splitting Constant in Distonoid Anion-Radical Sc3N@C80−, and Spatial Spin-Charge Separation as a General Principle for Anions of Endohedral Fullerenes with Metal-Localized Lowest Unoccupied Molecular Orbital. J. Am. Chem. Soc. 2008, 130 (52), 17726-17742. DOI: 10.1021/ja804226a
S. Yang, A. Popov, L. Dunsch. An Exception to the Isolated Pentagon Rule (IPR): The Endohedral Non-IPR C70 Cage of Sc3N@C70. Angew. Chem. Int. Ed. 2007, 46 (8), 1256-1259. DOI: 10.1002/anie.200603281
M. Krause, F. Ziegs, A. A. Popov, L. Dunsch. Entrapped Bonded Hydrogen in a Fullerene: the Five-Atom Cluster Sc3CH in C80. ChemPhysChem 2007, 8, 537-540. DOI: 10.1002/cphc.200600363
A. Popov, M. Krause, S. Yang, J. Wong, L. Dunsch. C78 cage isomerism defined by trimetallic nitride cluster size: a computational and vibrational spectroscopic study. J. Phys. Chem. B 2007, 111, 3363-3369. DOI: 10.1021/jp068661r
I. E. Kareev, N. B. Shustova, D. V. Peryshkov, S. F. Lebedkin, S. M. Miller, O. P. Anderson, A. A. Popov, O. V. Boltalina, S. H. Strauss. X-ray structure and DFT study of C1-C60(CF3)12. A high-energy, kinetically-stable isomer prepared at 500 °C. Chem. Commun. 2007, (16), 1650-1652. DOI: 10.1039/B617489B
A. M. Lebedev, K. A. Menshikov, V. G. Stankevich, N. Yu. Svechnikov, A. A. Popov, O. V. Boltalina, O. Drozdova, S. Kimura. Polarized IR studies of C60F18 single crystals. Diam. Relat. Mater. 2007, 16 (4-7), 1236-1239. DOI: 10.1016/j.diamond.2006.11.093
N. B. Shustova, B. S. Newell, S. M. Miller, O. P. Anderson, R. D. Bolskar, K. Seppelt, A. A. Popov, O. V. Boltalina, S. H. Strauss. Discovering and Verifying Elusive Fullerene Cage Isomers: Structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C78-D3h(5))(CF3)12. Angew. Chem. Int. Ed. 2007, 46 (8), 4111-4114. DOI: 10.1002/anie.200604968
N. B. Shustova, D. V. Peryshkov, A. A. Popov, O. V. Boltalina, S. H. Strauss. 1,6,11,18,24,27,33,51,54,60-Decakis(trifluoromethyl)-1,6,11,18,24,27,33,51,54,60-decahydro(C60-Ih)[5,6]fullerene. Acta Cryst. E 2007, E63, o3129. DOI: 10.1107/S1600536807026128
V. I. Korepanov, A. A. Popov, V. M. Senyavin, M. A. Yurovskaya, E. S. Chernyshova. Infrared spectrum and structure of 2-thienyl-N-methylfulleropyrrolidine. Moscow Univ. Chem. Bull. 2007, 62, 72-78. DOI: 10.3103/S0027131407020034 (В. И. Корепанов, А. А. Попов, В. М. Сенявин, М. А. Юровская, Э. С. Чернышова. ИК спектр и структура 2-тиенил-N-метил-фуллеренопирролидина. Вестн. Моск. Ун-та. Сер. 2. Химия 2007, 48 (2), 86-94).
A. A. Popov, I. E. Kareev, N. B. Shustova, E. B. Stukalin, S. F. Lebedkin, K. Seppelt, S. H. Strauss, O. V. Boltalina, L. Dunsch. Electrochemical, Spectroscopic, and DFT Study of C60(CF3)n Frontier Orbitals (n = 2-18): The Link between Double Bonds in Pentagons and Reduction Potentials. J. Am. Chem. Soc. 2007, 129 (37), 11551-11568. DOI: 10.1021/ja073181e
N. B. Shustova, A. A. Popov, M. A. Mackey, C. E. Coumbe, J. P. Phillips, S. Stevenson, S. H. Strauss, O. V. Boltalina. Radical Trifluoromethylation of Sc3N@C80. J. Am. Chem. Soc. 2007, 129 (38), 11676-11677. DOI: 10.1021/ja074332g
A. A. Popov, L. Dunsch. Structure, Stability, and Cluster-Cage Interactions in Nitride Clusterfullerenes M3N@C2n (M = Sc, Y; 2n = 68-98): a Density Functional Theory Study. J. Am. Chem. Soc. 2007, 129 (38), 11835-11549. DOI: 10.1021/ja073809l
Y. Kobayashi, A. A. Popov, S. M. Miller, O. P. Anderson, S. H. Strauss. Synthesis and Structure of Ag(1-Me-12-SiPh3-CB11F10): Selective F12 Substitution in 1-Me-CB11F11- and the First Ag(arene)4+ Tetrahedron. Inorg. Chem. 2007, 46 (21), 8505-8507. DOI: 10.1021/ic701606p
S. Yang, A. A. Popov, L. Dunsch. The Role of an Asymmetric Nitride Cluster on a Fullerene Cage: The Non-IPR Endohedral DySc2N@C76. J. Phys. Chem. B 2007, 111 (49), 13659-13663. DOI: 10.1021/jp709650d
A. A. Popov, I. E. Kareev, N. B. Shustova, S. F. Lebedkin, S. H. Strauss, O. V. Boltalina, L. Dunsch. Synthesis, Spectroscopic and Electrochemical Characterization, and DFT Study of Seventeen C70(CF3)n Derivatives (n = 2, 4, 6, 8, 10, 12). Chem. Eur. J. 2007, 14 (1), 107-121. DOI: 10.1002/chem.200700970
E. I. Dorozhkin, D. V. Ignat’eva, N. B. Tamm, A. A. Goryunkov, P. A. Khavrel, I. N. Ioffe, A. A. Popov, I. V. Kuvychko, A. V. Streletskiy, V. Y. Markov, J. Spandl, S. H. Strauss, O. V. Boltalina. Synthesis, Characterization, and Theoretical Study of Stable Isomers of C70(CF3)n (n = 2, 4, 6, 8, 10). Chem. Eur. J. 2006, 12, 3876–3889. DOI: 10.1002/chem.200501346
Y. Kobayashi, S. V. Ivanov, A. A. Popov, S. M. Miller, O. P. Anderson, K. A. Solntsev, S. H. Strauss. Tetrabutylammonium salt of the B24F224– anion. Two B12F112– icosahedra linked by a 2c-2e B-B bond and surrounded by a sheath of CH···FB hydrogen bonds. Heteroatom Chemistry 2006, 17 (3), 181-187. DOI: 10.1002/hc.20220
I. E. Kareev, S. F. Lebedkin, A. A. Popov, S. M. Miller, O. P. Anderson, S. H. Strauss, O. V. Boltalina. 1,6,12,15,18,23,25,41,45,57-Decakis(trifluoromethyl)-1,6,12,15,18,23,25,41,45,57-decahydro(C60–Ih)[5,6]fullerene. Acta Cryst. E 2006, E62, o1501–o1503. DOI: 10.1107/S1600536806008300
A. A. Popov, V. M. Senyavin, S. I. Troyanov. Electronic Structure and Spectroscopic Studies of D3d-C60Cl30, a Chlorofullerene with a [18]Trannulene Ring, and Its Relation to Other [18]Trannulenes. J. Phys. Chem. A. 2006, 110(23), 7414-7421. DOI: 10.1021/jp060522m
A. A. Popov, V. M. Senyavin, O. V. Boltalina, K. Seppelt, J. Spandl, C. S. Feigerle, R. N. Compton. Infrared, Raman, and DFT Vibrational Spectroscopic Studies of C60F36 and C60F48. J. Phys. Chem. A 2006, 110(28), 8645-8652. DOI: 10.1021/jp060697w
M. Krause, A. Popov, L. Dunsch. Vibrational Structure of Endohedral Fullerene Sc3N@C78 (D3h’) – Evidence for a Strong Coupling between the Sc3N cluster and C78 Cage. ChemPhysChem 2006, 7 (8), 1734-1740. DOI: 10.1002/cphc.200600139
S. Yang, M. Kalbac, A. Popov, L. Dunsch. Gadolinium-Based Mixed-Metal Nitride Clusterfullerenes GdxSc3-xN@C80 (x=1, 2). ChemPhysChem 2006, 7 (9), 1990-1995. DOI: 10.1002/cphc.200600323
M. V. Korobov, A. G. Bogachev, V. M. Senyavin, A. A. Popov, V. A. Davydov, A. V. Rakhmanina, A. V. Markin. Equilibrium Phase Diagram of Polymerized C60 and Kinetics of Decomposition of the Polymerized Phases. Fullerenes Nanotubes Carbon Nanostr. 2006, 14 (2-3), 401–407. DOI: 10.1080/10407780600665983
S. Yang, M. Kalbac, A. Popov, L. Dunsch. A Facile Route to the Non-IPR Fullerene Sc3N@C68: Synthesis, Spectroscopic Characterization, and Density Functional Theory Computations (IPR=Isolated Pentagon Rule). Chem. Eur. J. 2006, 12, 7856–7863. DOI: 10.1002/chem.200600261
I. E. Kareev. N. B. Shustova, I. V. Kuvychko, S. F. Lebedkin, S. M. Miller, O. P. Anderson, A. A. Popov, S. H. Strauss, O. V. Boltalina, O. V. Thermally Stable Perfluoroalkylfullerenes with the Skew-Pentagonal-Pyramid Pattern: C60(C2F5)4O, C60(CF3)4O, and C60(CF3)6. J. Am. Chem. Soc. 2006, 128 (37), 12268-12280. DOI: 10.1021/ja063907r
A. A. Goryunkov, I. E. Kareev, I. N. Ioffe, A. A. Popov, I. V. Kuvychko, V. Y. Markov, I. V. Goldt, A. S. Pimenova, M. G. Serov, S. M. Avdoshenko, P. A. Khavrel, L. N. Sidorov, S. F. Lebedkin, Z. Mazej, B. Žemva, S. H. Strauss, O. V. Boltalina. Reaction of C60 with KMnF4: Isolation and characterization of a new isomer of C60F8 and re-evaluation of the structures of C60F7(CF3) and the known isomer of C60F8. J. Fluor. Chem. 2006, 1423-1435. DOI: 10.1016/j.jfluchem.2006.06.016
N. B. Shustova, I. V. Kuvychko, R. D. Bolskar, K. Seppelt, S. H. Strauss, A. A. Popov, O. V. Boltalina. Trifluoromethyl Derivatives of Insoluble Small-HOMO-LUMO-Gap Hollow Higher Fullerenes. NMR and DFT Structure Elucidation of C2-(C74-D3h)(CF3)12, Cs-(C76-Td(2))(CF3)12, C2-(C78-D3h(5))(CF3)12, Cs-(C80-C2v(5))(CF3)12, and C2-(C82-C2(5))(CF3)12. J. Am. Chem. Soc. 2006, 128(49), 15793-15798. DOI: 10.1021/ja065178l
S. Yang, S. I. Troyanov, A. A. Popov, M. Krause, L. Dunsch. Deviation from the Planarity-a Large Dy3N Cluster Encapsulated in an Ih-C80 Cage: An X-ray Crystallographic and Vibrational Spectroscopic Study. J. Am. Chem. Soc. 2006; 128, 16733-16739. DOI: 10.1021/ja066814i
S. I. Troyanov, N. B. Shustova, A. A. Popov, L. N. Sidorov, E. Kemnitz. The First Preparation and Structural Characterization of Two Kinetically Stable Chlorofullerenes, C60Cl28 and C60Cl30. Angew. Chem. Int. Ed. 2005, 44, 432-435. DOI: 10.1002/anie.200462139
M. V. Korobov, A. G. Bogachev, A. A. Popov, V. M. Senyavin, E. B. Stukalin, A. V. Dzyabchenko, V. A. Davydov, L. S. Kashevarova, A. V. Rakhmanina, V. Agafonov. Relative stability of polymerized phases of C60: Depolymerization of a tetragonal phase. Carbon 2005, 43, 954-961. DOI: 10.1016/j.carbon.2004.11.026
N. B. Shustova, A. A. Popov, L. N. Sidorov, A. P. Turnbull, E. Kemnitz, S. I. Troyanov. Preparation and crystallographic characterization of C60Cl24. Chem. Comm. 2005, 1411-1413. DOI: 10.1039/B416341A
A. B. Kolomeisky, E. B. Stukalin, A. A. Popov. Understanding mechanochemical coupling in kinesins using first-passage-time processes. Phys. Rev. E 2005, 71, 031902. DOI: 10.1103/PhysRevE.71.031902
S. I. Troyanov, A. A. Popov. New [70]Fullerene Chloride, C70Cl16, Obtained by the Attempted Bromination of C70 in TiCl4. Angew. Chem. Int. Ed. 2005, 44, 4215-4218. DOI: 10.1002/anie.200500476
I. V. Kuvychko, A. V. Streletskii, A. A. Popov, S. G. Kotsiris, T. Drewello, S. H. Strauss, O. V. Boltalina. Seven-Minute Synthesis of Pure Cs-C60Cl6 from [60]Fullerene and Iodine Monochloride. First IR, Raman, and Mass Spectra of 99 mol% C60Cl6. Chem. Eur. J. 2005, 11 (18), 5426–5436. DOI: 10.1002/chem.200500185
M. R. Erenburg, A. A. Popov, O. A. Semenikhin. Spectroelectrochemical Properties of Some Polymers of Polythiophene Series. Russian Journal of Electrochemistry 2005, 41 (6), 671–680. (М.Р. Эренбург, А.А. Попов, О.А. Семинихин. Спектроэлектрохимические свойства некоторых полимеров ряда политиофена. Электрохимия 2005, 41(6), 755–765.).
A. A. Popov, J. Tarabek, I. E. Kareev, S. F. Lebedkin, S. H. Strauss, O. V. Boltalina, L. Dunsch. Poly(trifluoromethyl)fullerene Radical Anions. An ESR/Vis-NIR Spectroelectrochemical Study of C60F2,4 and C60(CF3)2,10. J. Phys. Chem. A 2005, 109 (43), 9709-9711. DOI: 10.1021/jp0550006
S. I. Troyanov, N. B. Shustova, A. A. Popov, L. N. Sidorov. Synthesis and Structures of C60 Fullerene Chlorides. Russ. Chem. Bull., Int. Ed. 2005, 7, 1656–1666. DOI: 10.1007/s11172-006-0018-4 (С. И. Троянов, Н. Б. Шустова, А. А. Попов, Л. Н. Сидоров. Синтез и строение хлоридов фуллерена С60. Изв. Акад. Наук., Сер. Хим. 2005, 7, 1608-1618.)
I. E. Kareev, I. V. Kuvychko, A. A. Popov, S. F. Lebedkin, S. M. Miller, O. P. Anderson, S. H. Strauss, O. V. Boltalina. High-Temperature Synthesis of the Surprisingly Stable C1-C70(CF3)10 Isomer with a para7-meta-para Ribbon of Nine C6(CF3)2 Edge-Sharing Hexagons. Angew. Chem. Int. Ed., 2005, 44 (48), 7984-7987. DOI: 10.1002/anie.200502419
J. V. Rau, S. Nunziante Cesaro, O. V. Boltalina, V. Agafonov, A. A. Popov, L. N. Sidorov. Raman and Infrared Spectroscopic Study of C60F18, C60F36 and C60F48. Vibrational Spectroscopy 2004, 34, 137-147. DOI: 10.1016/j.vibspec.2003.05.003
A. A. Popov, V. M. Senyavin, A. A. Granovsky. Vibrations of Bromofullerene C60Br24: C60 Cage Confined Into Static Bromine Sphere. Chem. Phys. Lett. 2004, 383, 149-155. DOI: 10.1016/j.cplett.2003.10.144
V. I. Korepanov, A. A. Popov, V. M. Senyavin, M. Reinov, M. A. Yurovskaya. Infrared Spectra and Structure of C60 Heterocyclic Derivatives. Fullerenes Nanotubes Carbon Nanostr. 2004, 12, 209-213. DOI: 10.1081/FST-120027158
V. M. Senyavin, A. A. Popov, A. A. Granovsky, V. A. Davydov, V. N. Agafonov. Ab initio and DFT-Based Assignment of the Vibrational Spectra of Polymerized Fullerenes. Fullerenes Nanotubes Carbon Nanostr. 2004, 12, 253-258. DOI: 10.1081/FST-120027165
A. A. Popov, V. M. Senyavin, A. A. Granovsky. Vibrational Spectra of Chloro- and Bromofullerenes. Fullerenes Nanotubes Carbon Nanostr. 2004, 12, 305-310. DOI: 10.1081/FST-120027184
N. I. Denisenko, S. I. Troyanov, A. A. Popov, I. V. Kuvychko, B. Zemva, E. Kemnitz, S. H. Strauss, O. V. Boltalina. Th-C60F24. J. Am. Chem. Soc. 2004, 126, 1618-1619. DOI: 10.1021/ja039361f
S. I. Troyanov, N. B. Shustova, A. A. Popov, M. Feist, E. Kemnitz. Chlorination of C60 and C70 Fullerenes Using SbCl5 and VCl4 Chlorides. Russ. J. Inorg. Chem. 2004, 49 (9), 1303–1307. (С. И. Троянов, Н. Б. Шустова, А. А. Попов, М. Файст, Э. Кемниц. Хлорирование фуллеренов C60 и C70 с использованием хлоридов SbCl5 and VCl4. Ж. Неорг. Хим. 2004, 49 (9), 1413–1418).
A. A. Popov, A. A. Goryunkov, I. V. Goldt, I. S. Kareev, I. V. Kuvychko, W.−D. Hunnius, K. Seppelt, S. H. Strauss, O. V. Boltalina. Raman, Infrared, and Theoretical Studies of Fluorofullerene C60F20. J. Phys. Chem. A 2004, 108, 11449-11456. DOI: 10.1021/jp046214a
S. I. Troyanov, A. A. Popov, N. I. Denisenko, O. V. Boltalina, L. N. Sidorov, E. Kemnitz. The First X-ray Crystal Structures of Halogenated [70]Fullerene: C70Br10 and C70Br10×3Br2. Angew. Chem. Int. Ed. 2003, 42, 2395-2398. DOI: 10.1002/anie.200351132
P. A. Troshin, D. Kolesnikov, A. V. Burtsev, R. N. Lubovskaya, N. I. Denisenko, A. A. Popov, S. I. Troyanov, O. V. Boltalina. Bromination of [60]Fullerene. I. High-Yield Synthesis of C60Brx (x = 6, 8, 24). Fullerenes Nanotubes Carbon Nanostr. 2003, 11, 47-60. DOI: 10.1081/FST-120018666
P. A. Dorozhko, A. S. Lobach, A. A. Popov, V. M. Senyavin, M. V. Korobov. Sublimation of Hydrofullerenes C60H36 and C60H18. Chem. Phys. Lett. 2001, 336, 39-46. DOI: 10.1016/S0009-2614(01)00103-8
R. G. Gasanov, O. G. Kalina, A. A. Popov, P. A. Dorozhko, B. L. Tumanskii. ESR Study of the photolysis of C60Cl6. Russ. Chem. Bull. 2000, 4, 753-753. DOI: 10.1007/BF02495497 (Р. Г. Гасанов, О. Г. Калина, А. А. Попов, П. А. Дорожко, Б. Л. Туманский Исследование методом ЭПР фотолиза C60Cl6. Изв. Акад. Наук., Сер. Хим. 2000, 4, 752-753).
P. A. Dorozhko, A. A. Popov, M. V. Korobov, B. L. Tumanskii. Stability of Gaseous Fullerene Chlorides. Chem. Phys. Lett. 1998, 287, 154-161. DOI: 10.1016/S0009-2614(98)00136-5
Reviews
F. Liu, L. Spree, D. S. Krylov, G. Velkos, S. M. Avdoshenko, A. A. Popov. Single-electron lanthanide-lanthanide bonds inside fullerenes toward robust redox-active molecular magnets. Acc. Chem. Res. 2019, 52 (10), 2981-2993. DOI: 10.1021/acs.accounts.9b00373
L. Spree, A. A. Popov. Recent advances in single molecule magnetism of dysprosium-metallofullerenes. Dalton Trans. 2019, 48, 2861. DOI: 10.1039/c8dt05153d
A. A. Popov. Redox-active metal–metal bonds between lanthanides in dimetallofullerenes. Curr. Opin. Electrochem. 2018, 8, 73-80. DOI: 10.1016/j.coelec.2017.12.003
O. V. Boltalina, A. A. Popov, I. V. Kuvychko, N. B. Shustova, S. H. Strauss. Perfluoroalkylfullerenes. Chem. Rev. 2015, 115, 1051-1105. DOI: 10.1021/cr5002595
Y. Zhang, A. A. Popov. Transition-Metal and Rare-Earth-Metal Redox Couples inside Carbon Cages: Fullerenes Acting as Innocent Ligands. Organometallics 2014, 33(18), 4537-4549. DOI: 10.1021/om5000387
A. A. Popov, S. Yang, L. Dunsch. Endohedral Fullerenes. Chem. Rev. 2013, 113 (8), 5989–6113. DOI: 10.1021/cr300297r
A. A. Popov, S. M. Avdoshenko, A. M. Pendás, L. Dunsch. Bonding between strongly repulsive metal atoms: an oxymoron made real in a confined space of endohedral metallofullerenes. Chem. Commun. 2012, 48, 8031-8050. DOI: 10.1039/C2CC32568C
A. A. Popov, L. Dunsch. Electrochemistry in Cavea: Endohedral Redox Reactions of Encaged Species in Fullerenes. J. Phys. Chem. Lett. 2011, 2 (7), 786-794. DOI: 10.1021/jz200063k
A. A. Popov. Metal-Cage Bonding, Molecular Structures and Vibrational Spectra of Endohedral Fullerenes: Bridging Experiment and Theory. J. Comput. Theor. Nanosci. 2009, 6 (2), 292-317. DOI: 10.1166/jctn.2009.1037
Book Chapters
In Endohedral Fullerenes: Electron Transfer and Spin. A.A. Popov (Editor). Springer International Publishing, 2017. DOI: 10.1007/978-3-319-47049-8
In New Fluorinated Carbons: Fundamentals and Applications. O. V. Boltalina, T. Nakajima (Eds.). Elsevier, 2017.
A.A. Popov. Endohedral Clusterfullerenes. in Carbon Nanomaterials Sourcebook: Graphene, Fullerenes, Nanotubes, and Nanodiamonds. Sattler, K. D. (Ed.) CRC Press, 2016; pp 303-333. link
P. Rapta, E. Dmitrieva, A. A. Popov, L. Dunsch. In Situ Spectroelectrochemistry of Organic Compounds. In Organic Electrochemistry, Fifth Edition, Hammerich, O.; Speiser, B., Eds. CRC Press: 2015; pp 169-190. link
In Endohedral Fullerenes. From Fundamentals to Applications. S. Yang, C.-R. Wang (Eds). World Scientific, 2014
A. A. Popov. Computational Studies of Endohedral Metallofullerenes in Endohedral Metallofullerenes: Basics and Applications. X. Lu, L. Echegoyen, A. L. Balch, S. Nagase, T. Akasaka (Eds.). CRC Press, 2014. link
A. A. Popov. Structures and Stability of Fullerenes, Metallofullerenes, and Their Derivatives in Handbook of Computational Chemistry. J. Leszczynski (Ed.) Springer, 2012, pp. 667-721. DOI: 10.1007/978-94-007-0711-5_19; 2nd edition in 2016: DOI: 10.1007/978-94-007-6169-8_19-2
In Strained Hydrocarbons: Beyond the van't Hoff and Le Bel Hypothesis H. Dodzik (Ed.), Wiley-VCH, Weinheim, 2009. DOI: 10.1002/9783527627134